Cu-Zn interaction regulating via heat treatment and the ultra-deep desulfurization for thiophene over Cu/ZnO sorbent

Zhang, Xiaoxia; Wang, Yongjin; Wei, Fanjing; Guo, Jiawei; Liao, Junjie; Chang, Liping; Bao, Weiren

doi:10.1016/j.fuel.2023.130432

Fuel

2024

DOI: 10.1016/j.fuel.2023.130432

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Cu-Zn interaction regulating via heat treatment and the ultra-deep desulfurization for thiophene over Cu/ZnO sorbent

Xiaoxia Zhang,

Yongjin Wang,

Fanjing Wei

et al.

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2024

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Cited by 3 publications

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Oxygen vacancy regulation on Cu-Zn oxides with Ce doping for enhancing ultra-deep removing of thiophene

Zhang,

Wang,

Liao

et al. 2024

Fuel

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Oxygen vacancy regulation on Cu-Zn oxides with Ce doping for enhancing ultra-deep removing of thiophene

Zhang,

Wang,

Liao

et al. 2024

Fuel

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Cu/ZnO/Al2O3 sorbent promoted by Zr for the ultra-deep removal of thiophene in simulated coke oven gas

Zhang,

Zhou,

Liao

et al. 2024

Separation and Purification Technology

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Enhancing Desulfurization Performance of Cu-Based Sorbents for Thiophene Removal via AlOOH-Assisted Synthesis

Wang,

Zhou,

Zhang

et al. 2024

Energy Fuels

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The preparation of a Cu-based sorbent supported by cost-effective AlOOH is proposed. A Cu-based sorbent for thiophene removal from coke oven gas was synthesized via coprecipitation, and the effect of AlOOH addition on the dispersion of activated Cu species and desulfurization properties was investigated. At an AlOOH content of 25%, smaller and more highly dispersed Cu grains, along with ZnO crystalline phases, were present on the surface of the Cu-based sorbent. The enhanced Cu-ZnO interaction contributed to the superior desulfurization performance (Q b-thiophene = 30.43 mg/g). The incorporation of an appropriate amount of AlOOH into the binary system during synthesis produces a highly active sorbent with superior Cu dispersion and smaller Cu grains, thereby fulfilling the requirements of industrial applications at a lower production cost.

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Cu-Zn interaction regulating via heat treatment and the ultra-deep desulfurization for thiophene over Cu/ZnO sorbent

Cited by 3 publications

References 42 publications

Oxygen vacancy regulation on Cu-Zn oxides with Ce doping for enhancing ultra-deep removing of thiophene

Oxygen vacancy regulation on Cu-Zn oxides with Ce doping for enhancing ultra-deep removing of thiophene

Cu/ZnO/Al2O3 sorbent promoted by Zr for the ultra-deep removal of thiophene in simulated coke oven gas

Enhancing Desulfurization Performance of Cu-Based Sorbents for Thiophene Removal via AlOOH-Assisted Synthesis

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