[Cu4OCl6(DABCO)2]·0.5DABCO·4CH3OH (“MFU-5”): Modular synthesis of a zeolite-like metal-organic framework constructed from tetrahedral {Cu4OCl6} secondary building units and linear organic linkers

Recent Advances in Zeolite‐like Cluster Organic Frameworks

“…[103] Additionally, Volkmer et al prepared the rare mso-type ZCOF [Cu 4 OCl 6 (dabco) 2 ]·0.5 DABCO·4CH 3 OH (MFU-5) formed by tetrahedralc opper clusters linked togetherb ym ixed bridges of [Cu II OCl 4 ] 4À andDABCO. [104]…”

Dicarboxylate assisted synthesis of the monoclinic heterometallic tetrathiocyanato bridged copper(II) and mercury(II) coordination polymer {Cu[Hg(SCN)4]} : Synthesis, structural, vibration, luminescence, EPR studies and DFT calculations

“…The reaction of Hg(SCN) 2 and copper(II) chloride in the presence of malonic acid mono-deprotonated by NaOH or the reaction of Hg(SCN) 2 [45]. So, it may be suggested that the malonates could control the formation of the crystal structure without entering the final product.…”

“…Research on the design and synthesis of crystalline coordination polymers is an active topic in current chemistry [1,2]. With regard to the possible correlation between structure and function [3][4][5][6][7][8], coordination polymers have gained attraction as promising materials of the future [9] with specifically tailored, useful properties, such as magnetism [10,11], electrical conductivity [12], non-linear optical behavior [13,14], luminescence [15,16], porosity and gas storage [17,18], or drug delivery [19].…”

Synthesis, structure and highly selective C3H8/CH4 and C2H6/CH4 adsorption of a (4,8)-c ternary flu-metal–organic framework based upon both [Sc4O2(COO)8] and [Cu4OCl6] clusters

“…40 Very interestingly, the [M 4 O 2 (COO) x S y ] (M = Cu 2+ , Sc 3+ ; S = solvent; x = 4 or 6; y = 2 or 4) clusters are found to be able to serve as the potential cubic 8-connected nodes and the Cu 4 OCl 6 cluster may act as the alternative tetrahedral 4-connected node, although they are rarely encountered in the construction of MOFs. 41–45…”

“…40 Very interestingly, the [M 4 O 2 IJCOO) x S y ] (M = Cu 2+ , Sc 3+ ; S = solvent; x = 4 or 6; y = 2 or 4) clusters are found to be able to serve as the potential cubic 8-connected nodes and the Cu 4 OCl 6 cluster may act as the alternative tetrahedral 4-connected node, although they are rarely encountered in the construction of MOFs. [41][42][43][44][45] Our group has great interest in the construction of MOFs based upon ligands containing N-heterocyclic and carboxyl groups and their environmental and energy related gas adsorption and separation properties. 1,[46][47][48][49][50][51][52][53] Herein, based upon the high-valence Sc 3+ ion being susceptible to coordination with the carboxyl group and the low-valence Cu 2+ ion being subject to coordination with the N-heteroatom, 36,37 The solvothermal reaction of ScCl 3 •6H 2 O and Cu(NO 3 ) 2 •3H 2 O with isonicotinic acid in the solution of N,N′dimethylformamide and acetonitrile at 120 °C successfully afforded a high yield of SNNU-Bai69 as yellow block crystals, which crystalize in the triclinic space group P1 ¯.…”