2008
DOI: 10.1021/cr0684321
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CuH-Catalyzed Reactions

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Cited by 637 publications
(302 citation statements)
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“…Copper catalysts can also catalyze various C─H and C-halogen activation reactions, and many of them involve intermediates with a Cu─C bond (36)(37)(38). These facts make copper catalysts a very promising choice for CO 2 transformation, especially with the formation of new C─C bonds.…”
Section: Resultsmentioning
confidence: 99%
“…Copper catalysts can also catalyze various C─H and C-halogen activation reactions, and many of them involve intermediates with a Cu─C bond (36)(37)(38). These facts make copper catalysts a very promising choice for CO 2 transformation, especially with the formation of new C─C bonds.…”
Section: Resultsmentioning
confidence: 99%
“…Bidentate phosphane ligands, such as bdp [5] and (S)-dtbm-segphos, [5] which are very effective ligands in copper-catalyzed hydrosilylation reactions, [6] were unsuccessful (Table 1, entries 8 and 9). Under the same reaction conditions as in Table 1, entry 6 (5 h), other silanes, such as Et 3 SiH, MePh 2 SiH, and Me(OEt) 2 SiH, afforded the product in trace, 2 %, and 51 % yields, respectively. An excess (5 equiv) of silane only slightly improved the yield, namely trace amounts with Et 3 SiH and 8 % using MePh 2 SiH.…”
mentioning
confidence: 99%
“…[2c] Herein, we report the use of extremely active copper catalysts [3] that contain bowl-shaped phosphane (bsp) ligands (2 or 3) in the hydrosilylation reaction of ketones. These catalysts afford the unprecedented preferential reduction of a bulky ketone substrate in the presence of an unprotected aldehyde.…”
mentioning
confidence: 99%
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“…[14,15] Die kupferkatalysierte Hydrosilylierung von Alkenen und Alkinen ist eine gut untersuchte Reaktion, für die das Auftreten von Zwischenstufen mit einer Cu-C-Bindung weithin akzeptiert wird. [16] Hier wurde ein solches Intermediat entworfen und in einer katalytischen Hydrocarboxylierung mit CO 2 eingesetzt. Die von Tsuji und Mitarbeiter beschriebene Hydrocarboxylierung von Alkinen führt auf einfache und elegante Weise unter milden Bedingungen zu a,b-ungesättigten Carbonsäu-ren.…”
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