2005
DOI: 10.1016/j.mseb.2004.05.043
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CuInS2 films deposited by aerosol-assisted chemical vapor deposition using ternary single-source precursors

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Cited by 17 publications
(5 citation statements)
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References 40 publications
(40 reference statements)
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“…Analysis of the organic products by GC/MS identified SePh 2 as the Ph-containing products in both experiments. While ternary materials have been prepared in this fashion (both alloys and compounds with well-defined M/M‘ lattice positions), the present compounds are distinctive in their combination of such dissimilar metals.…”
Section: Discussionmentioning
confidence: 99%
“…Analysis of the organic products by GC/MS identified SePh 2 as the Ph-containing products in both experiments. While ternary materials have been prepared in this fashion (both alloys and compounds with well-defined M/M‘ lattice positions), the present compounds are distinctive in their combination of such dissimilar metals.…”
Section: Discussionmentioning
confidence: 99%
“…mass-transport limited growth). [34][35][36][37] This results in a reduced number of small nucleation crystallites to which monomer ions are added along the (112) lattice plane influencing the growth of larger microstructures via coalescence of crystallites. Typically, a change in morphology is reflected in the intensity of the p-XRD reflections, 37 however a change in morphology at 450 °C does not deviate from the relative diffraction peak intensities of other samples which supports the preposition of coalescing crystallites which share a similar growth orientation as the emergent microstructure.…”
Section: Film Morphology and Compositionmentioning
confidence: 99%
“…These variations could be related to microstructure size, morphology, composition and constituent native defects. 37,45,46 However, it is more plausible to suggest that they are attributed to the influence on the density of states of valence and conduction bands as a consequence of elemental composition. 8,[45][46][47][48] Table 1: Optical properties and elemental composition (derived from EDS) of CIS thin films.…”
Section: Optical Propertiesmentioning
confidence: 99%
“…It was found that fi lms often contained a secondary phase (2 θ = 26.5 ° ), believed to be indium -rich (In -rich). 7 The more In -rich the fi lm, the more likely it was that the secondary phase was present, with the fi lm being more (204/220) oriented. EDS measurements (not shown) indicate that the fi lms containing the secondary phase were In -rich and that the Cu/In ratio increased when the secondary phase was reduced upon annealing [ Fig.…”
Section: Impact Of Reactor Design On C U I N S 2 Film Growthmentioning
confidence: 99%
“…The nature of the secondary In -rich phase was also confi rmed by Raman spectroscopy. 7 Processing conditions were sought to prevent the formation of the secondary phase, to favor growth conditions of (112) -oriented fi lms, and to avoid the surface kinetic regime where a (204/220) -oriented fi lm is favored. In our setup, for any reactor, the substrate temperature had to stay around 400 ° C in order to promote the growth of (112) -oriented fi lms without a high concentration of the In -rich secondary phase.…”
Section: Impact Of Reactor Design On C U I N S 2 Film Growthmentioning
confidence: 99%