One-dimensional semiconductor nanowires and nanorods have attracted increasing attention due to their physical properties arising from quantum confinement (such as electronic quantum transport and enhanced radiative recombination of carriers). However, increased surface-to-volume ratio and the role of nonradiative surface recombination would have to be dealt with. Nanowires could form the fundamental building blocks for applications such as short-wavelength nanolasers, field-effect transistors, ultrasensitive nano-sized gas sensors, nanoresonators, transducers, actuators, nanocantilevers, and field emitters (FEs) [1][2][3][4]. These nanostructures are ideal for studying transport mechanisms in one-dimensional systems, which are important not only for understanding the fundamental phenomena in lowdimensional systems, but also for developing new generation nanodevices with high performance. Many nanowires made of materials such as Si, C, InP, GaAs, CdS, SnO 2 , GaN, ZnO, and In 2 O 3 have been fabricated for different applications using mostly a catalyst-assisted vapor-liquid-solid (VLS) growth method (vapor-solid process if without the catalyst) [1, 2, 5, 6]. Among these materials, ZnO is considered to be the most promising one due to its large exciton binding energy (60 meV), high electromechanical coupling constant, and resistivity to harsh environment as well as the relative ease with which such structures can be produced with ZnO. Therefore, 1D ZnO structures stimulated a good deal of attention, and a large number of publications have appeared lately reporting nanostructures of various shapes (e.g., nanowires, nanobelts, nanorings, nanotubes, nanodonuts, nanopropellers, etc.) grown by different methods [1,2,. In this chapter, synthesis and properties of such nanostructures formed of ZnO are discussed. 7.