We report new measurements of the positronium (Ps) 2 3 S1 → 2 3 PJ fine-structure intervals, ν J (J = 0, 1, 2). In the experiments, Ps atoms, optically excited to the radiatively metastable 2 3 S1 level, flew through microwave radiation fields tuned to drive transitions to the short-lived 2 3 PJ levels, which were detected via the time spectrum of subsequent ground-state Ps annihilation radiation. Both the ν 1 and ν 2 line shapes were found to be asymmetric, which, in the absence of a complete line-shape model, prevents accurate determination of these fine-structure intervals. Conversely, the ν 0 line shape did not exhibit any significant asymmetry; the observed interval, however, was found to disagree with QED theory by 4.2 standard deviations.