“…The layered structure of A III B VI compounds, with weak polarisation bonds between packings, allows obtaining of single crystalline lamellae, with nano‐metric thickness, by cleavage of massive single crystals . These lamellae can be used as base elements in heterojunctions with optical contact, structures of semiconductor‐own oxide type and metal‐semiconductor contact . Both, the specifics of chemical bonds between the atoms of B‐A‐A‐B layered packings, and low density of surface states (≈10 10 cm −2 ), define the obtaining methods of 2D structures for nano‐lamellar electronic devices, ultrathin layer transistors, etc.…”