Climate change is currently the biggest environmental threat, being the cities responsible for a significant impact on greenhouse gas emissions. In this sense, the transport sector is among the main causes for both emissions and the depletion of non-renewable resources. Considering this scenario, there is an appeal to build more accessible, smart, sustainable and energy-efficient cities, promoting energy transition in urban systems and increasing the quality of urban life. This review aims to analyse transport and urban mobility studies that employ optimisation techniques to achieve environmental, sustainability or climate change mitigation goals. After an overview regarding modelling aspects of how such goals were addressed, the nature of the objective functions, the perspectives considered, and the network application, such studies were classified into five areas and further detailed. The areas comprise: (i) planning and policy-making; (ii) environmental variables; (iii) demand and traffic management; (iv) technology and energy; and (v) nonspatial measures. In this sense, future research directions should include optimisation models that consider the social aspects of transport and the interests of passengers, operators and the community simultaneously, improve the modelling of environmental impacts to increase its robustness, and deal with large network problems.INDEX TERMS Climate change, Greenhouse gas (GHG) emissions, Optimisation, Passenger urban transport, Sustainable mobility.