Phosphor-containing
white light-emitting diodes (LEDs) with low
color-correlated temperatures (CCTs) and high color rendering indexes
(CRIs) are highly desirable for energy-efficient and environmentally
friendly solid-state light sources. Here, we report a new and efficient
blue light-excited, green-emitting Ce3+-activated CaY2ZrScAl3O12 phosphor, which underpins
the fabrication of high-color quality and full-visible-spectrum warm-white
LED devices with ultrahigh CRI values (Ra > 96 and R9 > 96).
A family
of CaY2ZrScAl3O12:Ce3+ phosphors with different Ce3+ dopant concentrations were
prepared by high-temperature solid-state synthesis. X-ray diffraction
and corresponding Rietveld refinement reveal a garnet structure with
an Ia3̅d space group and crystallographic
parameters a = b = c = 12.39645(8) Å, α = β = γ = 90°, and V = 1904.99(4) Å3. Luminescence properties
were studied in detail as a function of Ce3+ with the optimal
concentration 1% mol. Impressively, CaY2ZrScAl3O12:1%Ce3+ exhibits a broad excitation band
from 370 to 500 nm, peaking at ∼421 nm, which is well matched
with emission from commercial blue LED chips. Under 421 nm excitation,
the CaY2ZrScAl3O12:1%Ce3+ phosphor produces dazzling green light in a wide emission band from
435 to 750 nm (emission peak: 514 nm; full width at half-maximum:
113 nm), with a high internal quantum efficiency of 63.1% and good
resistance to thermal quenching (activation energy of 0.28 eV). A
white LED device combining a 450 nm blue LED chip with CaY2ZrScAl3O12:1%Ce3+ green phosphor
and commercial CaAlSiN3:Eu2+ red phosphor as
color converters demonstrates bright warm-white light with excellent
CIE color coordinates of (0.3938, 0.3819), low CCT of 3696 K, high
CRI (Ra = 96.9, R9 = 98.2), and high luminous efficacy of 45.04 lm
W–1 under a 20 mA driving current. New green phosphors
enable the design and implementation of efficient luminescent materials
for healthy solid-state lighting.