Cyano disubstituted tetrabenzoindeno[2,1-a]fluorene: open-shell or closed-shell?
Priyank Kumar Sharma,
Palash Jana,
Subhajit Bandyopadhyay
et al.
Abstract:Organic diradicaloids have lately emerged as potential spintronic materials. We report the unprecedented synthesis of a near-IR absorbing indeno[2,1-a]fluorene derivative that displayed remarkably low LUMO (−4.15 eV) and a small...
Nakano et al. reported that the antiaromatic indenofluorene (IF) isomers are diradicaloid molecules having varying degrees of open-shell character, with indeno[1,2-b]fluorene displaying a weaker diradical character index (y0 = 0.072)....
Nakano et al. reported that the antiaromatic indenofluorene (IF) isomers are diradicaloid molecules having varying degrees of open-shell character, with indeno[1,2-b]fluorene displaying a weaker diradical character index (y0 = 0.072)....
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