The integration of Large Language Models (LLMs) with quantum-enhanced tools is revolutionizing cybersecurity. This chapter explores how these advanced technologies can address critical challenges, including real-time anomaly detection, advanced persistent threats (APTs), and zero-day exploits. By combining LLMs' contextual understanding with the computational power of quantum computing, we propose innovative approaches to strengthen intrusion detection systems, malware analysis, and threat intelligence. The chapter covers automated defense systems, adversarial scenario modeling, and adaptive cybersecurity frameworks that evolve in response to emerging threats. It highlights synergies between LLMs and quantum computing, presenting a dual strategy to detect and mitigate cyber risks more effectively. While discussing technical, ethical, and scalability challenges, the chapter offers practical insights for cybersecurity professionals, equipping them with tools and strategies to defend against increasingly sophisticated threats in a quantum-aware future.