Hydrogen can degrade the mechanical properties, particularly ductility, of metallic components. These hydrogen-induced degradation phenomena are generically called as Hydrogen Embrittlement (HE). There are significant problems associated with the HE of metallic components for clean energy. The scale is global and the present paucity of affordable hydrogen-proof materials poses strong technological and economic barriers to the hydrogen economy. Therefore, this doctoral dissertation aims to provide a deeper understanding of the influence of hydrogen on the properties of the targeted steels (NiCrMo1, 3.5NiCrMoV, 27NiCrMoV15-6 and 34CrNiMo6). These steels are typical quench and tempered steels, with strengths in the range of 700 to 1000 MPa. This dissertation comprises the following research works: (i) The influence of hydrogen on the tensile properties of the targeted steels; (ii) The influence of hydrogen on the fatigue properties of the typical steel-3.5NiCrMoV; (iii) The determination of the hydrogen fugacity during electrochemical charging at cathodic potentials using the low interstitial steel; (iv) The permeability of hydrogen and trapping effect on 3.5NiCrMoV steel. This research used the following techniques: optical microscopy, scanning electronic microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), electrochemical polarization, linearly increasing stress test (LIST), low cycle fatigue (LCF), fatigue crack growth (FCG) test, and permeation test. The LIST results indicated that all these four steels have good resistance to hydrogen embrittlement up to the yield stress, especially NiCrMo1, and each failed in the LISTs due to ductile overload. There was some HE, but only during the final ductile fracture, when the steel was mechanically unstable. HE was manifest in terms of the slightly lower value of R A %, the longer secondary cracks, the daisy-like surface features, and the brittle zone at the edge on the fracture surface. Lower ductility occurred associated with alumina oxide inclusions in the centre of daisy-like features. It is expected that the performance of the steels in a H environment could be improved by reducing the density or the size of inclusions. The main result from the LCF tests was that the reduction in fatigue life was significant for 3.5NiCrMoV, by about 60% ~ 90% in the presence of hydrogen, in terms of shortening the crack initiation period and accelerating the crack growth rate. There was no significant Publications during candidature