Equal channel angular pressing (ECAP) is applied to investigate the microstructural evolution and mechanical properties of Cu-8 wt pct Ag alloy subjected to one to four passes via four different routes (A, B A , B C , and C). It is demonstrated that better mechanical properties, a higher fraction of high-angle boundaries, and a smaller grain size can be obtained most rapidly with route A, whereas the specimen processed by route B C contains relatively inhomogeneous microstructure and has poor mechanical properties. The ultimate tensile stress (UTS) of the Cu-Ag alloy processed by route B C saturates after four passes; in contrast, the UTS of the Cu-Ag alloy processed by route A increases continuously in relation to the number of ECAP passes. Based on the experimental results, the strengthening mechanisms of the Cu-8 wt pct Ag alloy processed by different routes as well as the efficiency of different routes in refining the binary alloy are discussed.