Cycling profile of MgAl2O4-incorporated composite electrolytes composed of PEO and LiPF6 for lithium polymer batteries

“…Fig. 8 shows satisfactory capacity retention of a MgAl 2 O 4 /PEO membrane separator with specific capacity around 110 mAh/g after 100 cycles [132].…”

Section: Super Acid Oxidesmentioning

confidence: 97%

Polymer composites and blends for battery separators: State of the art, challenges and future trends

Nunes-Pereira

Costa

Lanceros‐Méndez

2015

Journal of Power Sources

243

145

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“…It is observed that the value of t + of P7 electrolyte is higher than that of P3 and S5 electrolytes. According to Angulakshmi et al [57], the increase in t + value may be attributed to the increasing salt dissociation. From our previous report [19], the addition of glycerol up to 35 wt.% enhances the conductivity since it promotes the salt dissociation which increases the number density of ion.…”

Section: Transference Number Analysismentioning

confidence: 96%

Hydrogen ion conducting starch-chitosan blend based electrolyte for application in electrochemical devices

Shukur

Kadir

2015

Electrochimica Acta

174

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“…The most extensively studied polymer host for solid polymer electrolyte applications is PEO. SPEs based on PEO have a series of specific features, such as low cost, good chemical stability and safety [6] and also high electrochemical stability in comparison with other polyethers, copolymers or PEO-branched polymers [7].…”

Section: Introductionmentioning

confidence: 99%

New solid polymer electrolytes (PEO20–LiTDI–SN) for lithium batteries: structural, thermal and ionic conductivity studies

Polu

Rhee

Kim

2015

J Mater Sci: Mater Electron

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Solid polymer electrolyte films based on Poly(ethylene oxide) (PEO) have been prepared by solution casting technique using acetonitrile as a solvent. Succinonitrile (SN) was used as a plasticizer and lithium 4,5-dicyano-2-(trifluoromethyl)imidazole (LiTDI) as a doping salt. The following techniques such as X-ray diffraction (XRD), differential scanning calorimetry (DSC), thermo gravimetric analysis, AC-impedance analysis and linear sweep voltametry have been employed to characterize the prepared solid polymer electrolyte films. The crystalline and amorphous nature of polymer electrolytes was confirmed by XRD and DSC analysis respectively. The electrolyte film with 30 wt% of SN was thermally stable up to 260°C. The ionic conductivities of polymer electrolyte films were calculated from the AC-impedance analysis. The undoped PEO 20 -LiTDI electrolyte exhibited the ionic conductivity of 9.64 9 10 -7 S cm -1 and this value was increased to 2.83 9 10 -5 S cm -1 when 30 wt% of succinonitrile was added to PEO 20 -LiTDI electrolyte at 23°C. The temperature dependent conductivity obeys Arrhenius behavior and the activation energy decreased to 0.264 eV. The electrochemical stability of the optimum conducting composition is 4.3 V, which make it attractive as electrolyte for Li battery.

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Cycling profile of MgAl2O4-incorporated composite electrolytes composed of PEO and LiPF6 for lithium polymer batteries

Cited by 99 publications

References 41 publications

Polymer composites and blends for battery separators: State of the art, challenges and future trends

Polymer composites and blends for battery separators: State of the art, challenges and future trends

Hydrogen ion conducting starch-chitosan blend based electrolyte for application in electrochemical devices

New solid polymer electrolytes (PEO20–LiTDI–SN) for lithium batteries: structural, thermal and ionic conductivity studies

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