Cycloalkanes oxidation with O2 catalyzed by a novel metalloporphyrin-based covalent coupling structure with bimetallic catalytic centers through synergistic mode

Ni, Jia-Ye; Ding, Yan-Bo; Sun, Jing; Wu, Hong-Ke; Shen, Hai-Min; She, Yuan-Bin

doi:10.1016/j.catcom.2024.106876

Catalysis Communications

2024

DOI: 10.1016/j.catcom.2024.106876

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Cycloalkanes oxidation with O2 catalyzed by a novel metalloporphyrin-based covalent coupling structure with bimetallic catalytic centers through synergistic mode

Jia-Ye Ni,

Yan-Bo Ding,

Jing Sun

et al.

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2024

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Organic and Metal–Organic Polymer-Based Catalysts—Enfant Terrible Companions or Good Assistants?

Králik,

Koóš,

Markovič

et al. 2024

Molecules

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This overview provides insights into organic and metal–organic polymer (OMOP) catalysts aimed at processes carried out in the liquid phase. Various types of polymers are discussed, including vinyl (various functional poly(styrene-co-divinylbenzene) and perfluorinated functionalized hydrocarbons, e.g., Nafion), condensation (polyesters, -amides, -anilines, -imides), and additional (polyurethanes, and polyureas, polybenzimidazoles, polyporphyrins), prepared from organometal monomers. Covalent organic frameworks (COFs), metal–organic frameworks (MOFs), and their composites represent a significant class of OMOP catalysts. Following this, the preparation, characterization, and application of dispersed metal catalysts are discussed. Key catalytic processes such as alkylation—used in large-scale applications like the production of alkyl-tert-butyl ether and bisphenol A—as well as reduction, oxidation, and other reactions, are highlighted. The versatile properties of COFs and MOFs, including well-defined nanometer-scale pores, large surface areas, and excellent chemisorption capabilities, make them highly promising for chemical, electrochemical, and photocatalytic applications. Particular emphasis is placed on their potential for CO2 treatment. However, a notable drawback of COF- and MOF-based catalysts is their relatively low stability in both alkaline and acidic environments, as well as their high cost. A special part is devoted to deactivation and the disposal of the used/deactivated catalysts, emphasizing the importance of separating heavy metals from catalysts. The conclusion provides guidance on selecting and developing OMOP-based catalysts.

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Organic and Metal–Organic Polymer-Based Catalysts—Enfant Terrible Companions or Good Assistants?

Králik,

Koóš,

Markovič

et al. 2024

Molecules

View full text Add to dashboard Cite

show abstract

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Cycloalkanes oxidation with O2 catalyzed by a novel metalloporphyrin-based covalent coupling structure with bimetallic catalytic centers through synergistic mode

Cited by 1 publication

References 30 publications

Organic and Metal–Organic Polymer-Based Catalysts—Enfant Terrible Companions or Good Assistants?

Organic and Metal–Organic Polymer-Based Catalysts—Enfant Terrible Companions or Good Assistants?

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