In this study, industrial wastes,
which remain after aluminum extraction
from saline slags, were used as adsorbents. The aluminum saline slags
were treated under reflux with 2 mol/dm
3
aqueous solutions
of NaOH, H
2
SO
4
, and HCl for 2 h. After separation
by filtration, aqueous solutions containing the extracted aluminum
and residual wastes were obtained. The wastes were characterized by
nitrogen adsorption at −196 °C, X-ray diffraction, scanning
electron microscopy, and ammonia pulse chemisorption. The chemical
treatment reduced the specific surface area, from 84 to 23 m
2
/g, and the pore volume, from 0.136 to 0.052 cm
3
/g, of
the saline slag and increased the ammonia-adsorption capacity from
2.84 to 5.22 cm
3
/g, in the case of acid-treated solids.
The materials were applied for the removal of Acid Orange 7 and Acid
Blue 80 from aqueous solutions, considering both single and binary
systems. The results showed interesting differences in the adsorption
capacity between the samples. The saline slag treated with HCl rapidly
adsorbed all of the dyes present in solution, whereas the other materials
retained between 50 and 70% of the molecules present in solution.
The amount of Acid Orange 7 removed by the nontreated material and
by the material treated with NaOH increased in the presence of Acid
Blue 80, which can be considered as a synergistic behavior. The CO
2
adsorption of the solids at several temperatures up to 200
°C was also evaluated under dry conditions. The aluminum saline
slag presented an adsorption capacity higher than the rest of treated
samples, a behavior that can be explained by the specific sites of
adsorption and the textural properties of the solids. The isosteric
heats of CO
2
adsorption, determined from the Clausius–Clapeyron
equation, varied between 1.7 and 26.8 kJ/mol. The wastes should be
used as adsorbents for the selective removal of organic contaminants
in wastewater treatment.