Cyclopolymerization. Part XXXI. An attempt to control the reaction courses of the polymerizations of N-methyl-N-allyl-2-(ethoxycarbonyl)allylamine by using anionic and radical initiators

Urushisaki, Michio; Kodaira, Toshiyuki; Takahashi, Hiroshi; Hashimoto, Tamotsu

doi:10.1016/j.polymer.2003.08.034

Polymer

2003

DOI: 10.1016/j.polymer.2003.08.034

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Cyclopolymerization. Part XXXI. An attempt to control the reaction courses of the polymerizations of N-methyl-N-allyl-2-(ethoxycarbonyl)allylamine by using anionic and radical initiators

Michio Urushisaki

Toshiyuki Kodaira

Hiroshi Takahashi

et al.

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2007

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Synthesis, characterization, and cyclopolymerization of a functional non-symmetric divinyl monomer

Dizman¹,

Mathias²

2007

Polymer

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A non-symmetric divinyl monomer with a terminal carboxylic acid functionality was readily synthesized from the reaction of ethyl α-hydroxymethylacrylate (EHMA) with maleic anhydride. The new monomer (EHMA-MA) was homopolymerized in both bulk and ethyl acetate using AIBN as an initiator to give cyclopolymers. The synthesis of the monomer and cyclopolymers were followed by 13 C NMR, 1 H NMR, and FTIR. 1 H NMR was also utilized to obtain the degree of cyclization of the polymers, which were found to be 95% or higher in all cases. The molecular weights of the cyclopolymers were around 40-60,000 g/mol as estimated by SEC. The cyclopolymers were thermally stable up to 150 o C. Although the cyclopolymers obtained were not water-soluble; they were soluble in aqueous 1M NaOH solution. In addition to the carboxylic acid functionality present, the cyclopolymers also had an ethyl ester and a lactone moiety. These functional groups were reacted with hexylamine to obtain a polymer with imide and amide moieties.

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Synthesis, characterization, and cyclopolymerization of a functional non-symmetric divinyl monomer

Dizman¹,

Mathias²

2007

Polymer

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Cyclopolymerization. Part XXXI. An attempt to control the reaction courses of the polymerizations of N-methyl-N-allyl-2-(ethoxycarbonyl)allylamine by using anionic and radical initiators

Cited by 1 publication

References 14 publications

Synthesis, characterization, and cyclopolymerization of a functional non-symmetric divinyl monomer

Synthesis, characterization, and cyclopolymerization of a functional non-symmetric divinyl monomer

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