Cyclotriphosphazene-based flame-retardant polymer electrolytes for high performance sodium metal batteries

Phosphorus–nitrogen compounds: part 68. Synthesis, characterization, stereogenism, photophysical and bioactivity studies of novel unsymmetrical dispiro(N/N)cyclotriphosphazenes with carbazolyl and 4-chlorobenzyl pendant arms

“…30 They are also used in applications such as bioimaging, delivering drugs and bioactive molecules, specific recognition, biomimetic catalysis 27 and potentially used as lubricants, 31 inflammable textile fibers, 32 membranes, 33 and electrolytes for sodium metal batteries. 34…”

“…30 They are also used in applications such as bioimaging, delivering drugs and bioactive molecules, specific recognition, biomimetic catalysis 27 and potentially used as lubricants, 31 inflammable textile fibers, 32 membranes, 33 and electrolytes for sodium metal batteries. 34 On the other hand, the carbazole scaffold is one of the pharmacologically active planar heterocyclic rings. Carbazole derivatives occupy an important position as remarkable vehicles not only for their antioxidant, antibacterial, anti-inflammatory and antitumor properties [35][36][37][38] but also for their photophysical properties.…”

Coupling Anion‐Capturer with Polymer Chains in Fireproof Gel Polymer Electrolyte Enables Dendrite‐Free Sodium Metal Batteries

“…However, most of currently reported GPEs using carbonate or ether solvent are still highly flammable, which make them inapplicable in large-scale energy storage system. [27,28] Recently, nonflammable organic phosphates with low viscosity, good solvating ability, wide electrochemical window, and low cost were chosen as solvents for electrolyte. [29] For example, Chen et.al tried to replace the solvent with nonflammable triethyl phosphate, [30] and prepared a flexible PPEGMA-based GPE via in situ thermal curing technique, which exhibited outstanding flame retardancy and electrochemical performances.…”

Efficiently predicting and synthesizing intrinsic highly fire-safe polycarbonates with processability

“…[1][2][3][4] Therefore, high re-safety in terms of low heat release, low smoke release and thermal runaway prevention capabilities, is a prerequisite for polymers applied in many elds, especially in aerospace, rail transit, new energy vehicles, etc. [5][6][7][8] The traditional manner for improving re-safe performance is the addition of ame retardants to the polymer matrix, such as compounds containing chlorine, bromine, phosphorus and silicon elements, [9][10][11][12][13] which have been employed but debated, tracked and evaluated for decades, since these additives cause migration and release problems during use, disposal and recycling as well as hazards to health and the environment. [14][15][16] In contrast, molecular design of re-safe polymers is a durable, environmentally benign strategy, the essence of which is to balance various properties and achieve optimization.…”