Atmospheric aerosol pollutants are considered for the first time for the durability evaluation of non-metallic photovoltaic materials on the example of pristine and Al 2 O 3 -encapsulated Al-doped zinc oxide (AZO) window layers. The AZO samples were exposed to a varied temperature and humidity cycle, completed or not by a daily deposition of (NH 4 ) 2 SO 4 or NaCl aerosols, typical pollutants in rural and marine environments, respectively. The samples exposed with and without the pollutants were compared after 1 and 2 weeks of the test. Optical transmittance and conductivity significantly degraded only for the samples exposed with the pollutants. Raman