Two - component / Double Diffusive Marangoni (DDM) convection with Dufour effects, in a two-layered system, has been studied analytically by using Darcy – Brinkmann Model. For fluid layer, the upper boundary is free with surface tension depending on both temperature and concentration, for porous layer the lower boundary is rigid and both the boundaries are insulating to both heat and mass. At the interface, the normal velocity, normal stress, shear stress, mass, mass flux, heat, heat flux is assumed to be continuous. The effect of different physical parameters on DDM convection is investigated in detail and results are presented graphically. The effect of Dufour parameter, which plays vital role in diffusion-thermal process, when the energy flux due to mass gradient appears, on DDM convection in a two- layer system, has been explored.