Darstellung und Charakterisierung von Eisenkomplexen, entstanden aus der Reaktion von [(C5R5)Fe(CO)2]2 (R = H, Me) mit phosphoryliden

Caballero, Celia R.; Chávez, Jorge; Göknur, Ömer; Löchel, Inge; Nuber, Bernd; Pfisterer, Heike; Ziegler, Manfred L.; Alburquerque, Pia R.; Eguren, Liliana; Korswagen, Richard

doi:10.1016/0022-328x(89)85229-5

Cited by 10 publications

(1 citation statement)

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“…Selected from the main group IVA are silicon-iron [ 748 – 752 ], silicon-iron and silicon-germanium [ 753 ], germanium-iron [ 745 ], and tin-iron [ 755 ] complexes. Selected from group VA are nitrogen-iron [ 756 , 757 ], phosphorus-iron [ 758 – 764 ], phosphorus-arsenic-iron [ 765 ], and tin-iron [ 766 – 768 ] complexes. Complexes containing iron and main-group elements from group VIA have also attracted considerable interest; these are sulfur-iron [ 769 – 786 ], sulfur-selenium-iron [ 787 ], and selenium-tellurium-iron [ 788 ] complexes.…”

Section: Addendamentioning

confidence: 99%

New chemical and stereochemical applications of organoiron complexes

Fatiadi

1991

J. RES. NATL. INST. STAN.

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The objective of this review is to provide a current overview of the rapidly developing chemistry of organometallic complexes and particularly organoiron complexes useful in asymmetric and stereoselective reactions. Also covered are stereoselective reactions of α, β-unsaturated acyl ligands bound to the chiral auxiliary [(η5-C5H5) Fe(CO)(PPh3)] and new applications of organoiron complexes in the synthesis of natural products. The mechanistic aspects and stabilizing effects of the Fe(CO)3 group for alkenes or conjugated dienes are discussed. A brief summary of recent work on the special role of iron in biological reactions is also included.

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