In this paper, the coupled heat and mass transfer within porous media has been studies. First, the studied materials have been characterized experimentally and than evaluated their thermal properties, namely thermal conductivity and specific heat in different states (dry-wet). The hygroscopic properties, namely water vapour permeability, water vapour sorption. At second time, we present and validate the mathematical model describing heat and mass transfer within bio-based materials, by the confrontation with the experimental results. The materials properties obtained from the characterisation part are used as model's input parameters. Moreover, a test facility is mounted in the laboratory in order to compare the numerical and experimental data. The founded results show a good concordance between the simulated and measured data. According to this results the mathematical model of Philip and de Vries gives a good prediction of hygrothermal behaviour of biobased material. This model will allow us to save money and time of the experimental part in the future.