Dauresorcinols A and B, two pairs of merosesquiterpenoid enantiomers with new carbon skeletons from Rhododendron dauricum

Zhang, Hanqi; Gao, Biao; Zheng, Guijuan; Feng, Yuanyuan; Liu, Zhijun; Yao, Guangmin

doi:10.1016/j.bioorg.2024.107428

Bioorganic Chemistry

2024

DOI: 10.1016/j.bioorg.2024.107428

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Dauresorcinols A and B, two pairs of merosesquiterpenoid enantiomers with new carbon skeletons from Rhododendron dauricum

Hanqi Zhang,

Biao Gao,

Guijuan Zheng

et al.

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2024

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Cited by 2 publications

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Minor Humulane and Eremophilane Sesquiterpenoids from Syringa pinnatifolia and Their Protective Effect Against Oxidative Injuries in H9c2 Cells

Sun,

Chen,

Liu

et al. 2024

Chemistry & Biodiversity

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As a part of systematic research, an ongoing phytochemical investigation of the sesquiterpenoid‐containing fraction led to the isolation of five new sesquiterpenoids from the peeled stems of Syringa pinnatifolia, including two pairs of enantiomeric humulane‐type (±)‐alashanoids A1 and B1 (1 and 2) and one eremophilane‐type alashanoid C1 (3). These structures were elucidated by the analysis of extensive spectroscopic data, including ESI‐MS and 1D and 2D NMR, and the absolute configuration was determined by comparing its experimental and calculated electronic circular dichroism and calculated NMR. These isolates exhibited moderate in vitro cardioprotective effects against oxidative injuries in H9c2 cells.

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Minor Humulane and Eremophilane Sesquiterpenoids from Syringa pinnatifolia and Their Protective Effect Against Oxidative Injuries in H9c2 Cells

Sun,

Chen,

Liu

et al. 2024

Chemistry & Biodiversity

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Hill,

Sutherland

2024

Nat. Prod. Rep.

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Dauresorcinols A and B, two pairs of merosesquiterpenoid enantiomers with new carbon skeletons from Rhododendron dauricum

Cited by 2 publications

References 34 publications

Minor Humulane and Eremophilane Sesquiterpenoids from Syringa pinnatifolia and Their Protective Effect Against Oxidative Injuries in H9c2 Cells

Minor Humulane and Eremophilane Sesquiterpenoids from Syringa pinnatifolia and Their Protective Effect Against Oxidative Injuries in H9c2 Cells

Hot off the press

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