Decatungstate-photocatalyzed radical addition of C(sp<sup>3</sup>)–H to azauracils

Qiao, Lipeng; Yang, Wumeng; Zhao, Xiangqian; Li, Erqing; Chen, Xiaolan; Qu, Lingbo; Yu, Bing

doi:10.1039/d4qo01339e

Org. Chem. Front.

2024

DOI: 10.1039/d4qo01339e

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Decatungstate-photocatalyzed radical addition of C(sp³)–H to azauracils

Lipeng Qiao,

Wumeng Yang,

Xiangqian Zhao

et al.

Abstract: This study presents a gentle and effective decatungstate ([W10O32]4−)-photocatalyzed method for the hydroalkylation of azauracils using a wide range of primary, secondary, and tertiary unreactive C–H bonds of alkanes as the alkylating reagents.

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Cited by 2 publications

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Decatungstate-Photocatalyzed Transformations of 2-Bromo-3,3,3-trifluoropropene for Selective Synthesis of Z/E-β-CF₃-Enones

Yuan,

Lu,

Huang

et al. 2024

Org. Lett.

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Condition-controlled switchable and divergent transformations of cost-effective 2-bromo-3,3,3-trifluoropropene (BTP) and aldehydes were realized using a decatungstate (TBADT)photocatalyzed strategy. The hydroacylated products, i.e., β,β-Br,CF 3 -ketones, can be applied as highly functionalized synthetic building blocks for the selective synthesis of (Z/E)-β-CF 3 -enones. Utilizing this methodology, a broad range of commercially available aromatic and aliphatic aldehydes as well as numerous complex aldehydes, such as lily aldehyde, cyclamen aldehyde, citronellal, vanillin, and aldehydes containing bioactive moieties, including ibuprofen, gemfibrozil, naproxen, flurbiprofen, oleic acid, and aspirin, may be proficiently employed in this transformative process.

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Decatungstate-Photocatalyzed Transformations of 2-Bromo-3,3,3-trifluoropropene for Selective Synthesis of Z/E-β-CF₃-Enones

Yuan,

Lu,

Huang

et al. 2024

Org. Lett.

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Photocatalyzed cascade hydrogen atom transfer for the construction of α-CF₃-1,4-diketones

Yuan,

Zheng,

et al. 2025

Org. Chem. Front.

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Decatungstate-photocatalyzed radical addition of C(sp³)–H to azauracils

Abstract: This study presents a gentle and effective decatungstate ([W10O32]4−)-photocatalyzed method for the hydroalkylation of azauracils using a wide range of primary, secondary, and tertiary unreactive C–H bonds of alkanes as the alkylating reagents.

Cited by 2 publications

References 61 publications

Decatungstate-Photocatalyzed Transformations of 2-Bromo-3,3,3-trifluoropropene for Selective Synthesis of Z/E-β-CF₃-Enones

Decatungstate-Photocatalyzed Transformations of 2-Bromo-3,3,3-trifluoropropene for Selective Synthesis of Z/E-β-CF₃-Enones

Photocatalyzed cascade hydrogen atom transfer for the construction of α-CF₃-1,4-diketones

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Decatungstate-photocatalyzed radical addition of C(sp3)–H to azauracils

Abstract: This study presents a gentle and effective decatungstate ([W10O32]4−)-photocatalyzed method for the hydroalkylation of azauracils using a wide range of primary, secondary, and tertiary unreactive C–H bonds of alkanes as the alkylating reagents.

Cited by 2 publications

References 61 publications

Decatungstate-Photocatalyzed Transformations of 2-Bromo-3,3,3-trifluoropropene for Selective Synthesis of Z/E-β-CF3-Enones

Decatungstate-Photocatalyzed Transformations of 2-Bromo-3,3,3-trifluoropropene for Selective Synthesis of Z/E-β-CF3-Enones

Photocatalyzed cascade hydrogen atom transfer for the construction of α-CF3-1,4-diketones

Contact Info

Product

Resources

About

Decatungstate-photocatalyzed radical addition of C(sp³)–H to azauracils

Decatungstate-Photocatalyzed Transformations of 2-Bromo-3,3,3-trifluoropropene for Selective Synthesis of Z/E-β-CF₃-Enones

Decatungstate-Photocatalyzed Transformations of 2-Bromo-3,3,3-trifluoropropene for Selective Synthesis of Z/E-β-CF₃-Enones

Photocatalyzed cascade hydrogen atom transfer for the construction of α-CF₃-1,4-diketones