Distributed stochastic optimization, arising in the crossing and integration of traditional stochastic optimization, distributed computing and storage, and network science, has advantages of high efficiency and a low per-iteration computational complexity in resolving large-scale optimization problems. This paper concentrates on resolving a large-scale convex finite-sum optimization problem in a multi-agent system over unbalanced directed networks. To tackle this problem in an efficient way, a distributed consensus optimization algorithm, adopting the push-sum technique and a distributed loopless stochastic variance-reduced gradient (LSVRG) method with uncoordinated triggered probabilities, is developed and named Push-LSVRG-UP. Each agent under this algorithmic framework performs only local computation and communicates only with its neighbors without leaking their private information. The convergence analysis of Push-LSVRG-UP is relied on analyzing the contraction relationships between four error terms associated with the multi-agent system. Theoretical results provide an explicit feasible range of the constant step-size, a linear convergence rate, and an iteration complexity of Push-LSVRG-UP when achieving the globally optimal solution. It is shown that Push-LSVRG-UP achieves the superior characteristics of accelerated linear convergence, fewer storage costs, and a lower per-iteration computational complexity than most existing works. Meanwhile, the introduction of an uncoordinated probabilistic triggered mechanism allows Push-LSVRG-UP to facilitate the independence and flexibility of agents in computing local batch gradients. In simulations, the practicability and improved performance of Push-LSVRG-UP are manifested via resolving two distributed learning problems based on real-world datasets.