Deciphering the Interplay between Local and Global Dynamics of Anodic Metal Oxidation
Aleksei Makogon,
Jean-Marc Noël,
Frédéric Kanoufi
et al.
Abstract:The stark difference between global and local metal oxidation dynamics underscores the need for methodologies capable of performing precise sub-μm-scale and wide-field measurements. In this study, we present reflective microscopy as a tool developed to address this challenge, illustrated by the example of chronoamperometric Fe oxidation in a NaCl solution. Analysis at a local scale of 10 s of μm has revealed three distinct periods of Fe oxidation: the initial covering of the metal interface with a surface film… Show more
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