Decomposition of allantoin in the presence of Cu(II) ions resulting in the formation of a coordination polymer containing oxalate species

Puszyńska-Tuszkanow, Mariola; Daszkiewicz, Marek; Maciejewska, Gabriela; Cieślak‐Golonka, Maria

doi:10.1016/j.inoche.2009.03.020

Inorganic Chemistry Communications

2009

DOI: 10.1016/j.inoche.2009.03.020

|View full text |Cite

Decomposition of allantoin in the presence of Cu(II) ions resulting in the formation of a coordination polymer containing oxalate species

Mariola Puszyńska-Tuszkanow¹,

Marek Daszkiewicz²,

Gabriela Maciejewska³

et al.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2012

2024

Publication Types

Select...

Article4

Relationship

Self Cite1

Independent3

Authors

Journals

Cited by 4 publications

References 35 publications

(28 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

Ni(II) complex with sarcosine derived from in situ generated ligand: structural, spectroscopic, and DFT studies

et al. 2015

Self Cite

View full text Add to dashboard Cite

Nickel(II) complex with sarcosine [Ni(sar) 2 (H 2 O) 2 ] (1) has been obtained as a reaction product of a system: Ni(II)Cl 2 -1-methylhydantoin. Basic hydrolysis of the organic substrate leads to in situ formation of sarcosine ligand, which coordinates to the metal ion. The isolated complex has been characterized by means of single crystal X-ray diffraction and spectroscopic studies (IR, Raman, and NIR-UV-Vis) supported with DFT calculations. Single crystal X-ray diffraction revealed that the nickel environment in [NiN 2 O 4 ] chromophore exhibited the geometry of a tetragonally elongated octahedron. Hydrogen bonds create two chain patterns which propagate along the main crystallographic directions a and b. It leads to the formation of a 2D network. Electronic spectra analysis showed that the nickel surroundings can be described as pseudooctahedral in solution and tetragonal in the solid state. Based on the calculated 10Dq parameter (10,990 cm -1 ), sarcosine ligand was located in the spectrochemical series close to ammonia. Comprehensive studies of the molecular structure and vibrational spectra of the title complex have been performed using UPBE0, unrestricted density functional method. The clear-cut assignment of the bands in FT-IR and Raman spectra of studied complex has been made on the basis of the calculated potential energy distribution. The Ni-L(sarcosine) stretching vibrations were assigned in Raman spectrum to the medium intensity band at 442 cm -1 .

show abstract

Ni(II) complex with sarcosine derived from in situ generated ligand: structural, spectroscopic, and DFT studies

et al. 2015

Self Cite

View full text Add to dashboard Cite

show abstract

Oxalato as polyatomic coordination center and magnetic coupler in copper(II)-polypyrazole inverse polynuclear complexes and coordination polymers

Castro

Calatayud

Orts-Arroyo

et al. 2022

Coordination Chemistry Reviews

View full text Add to dashboard Cite

Oxidative cleavage of 3-phenyllactic acid in presence of molybdenum complexes

Modec

Dolenc

2012

Inorganic Chemistry Communications

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Decomposition of allantoin in the presence of Cu(II) ions resulting in the formation of a coordination polymer containing oxalate species

Cited by 4 publications

References 35 publications

Ni(II) complex with sarcosine derived from in situ generated ligand: structural, spectroscopic, and DFT studies

Ni(II) complex with sarcosine derived from in situ generated ligand: structural, spectroscopic, and DFT studies

Oxalato as polyatomic coordination center and magnetic coupler in copper(II)-polypyrazole inverse polynuclear complexes and coordination polymers

Oxidative cleavage of 3-phenyllactic acid in presence of molybdenum complexes

Contact Info

Product

Resources

About