Decomposition of lithium amide and imide films on nickel

Engbæk, Jakob; Nielsen, Gunver; Nielsen, Linda; Chorkendorff, Ib

doi:10.1016/j.susc.2006.11.015

Cited by 8 publications

(2 citation statements)

References 23 publications

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“…The pioneering efforts of Chen et al in 2002 motivated extensive studies on the reversible hydrogen storage properties of lithium amide. − Alkali-metal amides have traditionally been used as reagents in synthetic organic chemistry. The original experiments for the synthesis of the wide variety of amides and their basic reactions related to hydrogen were systematically summarized by Bergstrom and Fernelius …”

Section: Amidesmentioning

confidence: 99%

Complex Hydrides for Hydrogen Storage

et al. 2007

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Section: Amidesmentioning

confidence: 99%

Complex Hydrides for Hydrogen Storage

et al. 2007

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“…The LiH phase forms during hydriding and is more stable than the other compounds involved at the temperature that we were performing the experiments (at 255 o C); however it would decompose at higher temperatures [147,148] also see Figure 4.17 above. The addition of nitrogen during hydriding facilitates the suppression of LiH formation.…”

Section: Effect Of Nitrogen In Cycling Gas On Hydriding Stabilitymentioning

confidence: 98%

Effect of Gaseous Impurities on Long-Term Thermal Cycling and Aging Properties of Complex Hydrides for Hydrogen Storage

Chandra¹,

Lamb²,

Chien³

et al. 2011

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Classical Hydrides (Example Metallic Hydrides AB 2 , AB 5 , A 2 B and other Hydrides)…….12 (2) Complex Hydrides (Alanates, Imide-Amide complexes, Borohydrides, and others)………12 (3) Chemical Hydrides (CH4, NH 3 , CH 3 OH, and others)…………………………….……......12 (4) Nanostructured molecular hydrogen sorption material (carbon nanotubes)…….……...…..13 (5) Current Hydrogen Storage Technology ………………………………………………..…..13 (6) Hydrogen Storage System Engineering Concerns ……………………………….………...13 II. Background …………………………………………………………………………….

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Ternary Amides Containing Transition Metals for Hydrogen Storage: A Case Study with Alkali Metal Amidozincates

et al. 2015

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The alkali metal amidozincates Li4 [Zn(NH2)4](NH2)2 and K2[Zn(NH2)4] were, to the best of our knowledge, studied for the first time as hydrogen storage media. Compared with the LiNH2-2 LiH system, both Li4 [Zn(NH2)4](NH2)2-12 LiH and K2[Zn(NH2)4]-8 LiH systems showed improved rehydrogenation performance, especially K2[Zn(NH2)4]-8 LiH, which can be fully hydrogenated within 30 s at approximately 230 °C. The absorption properties are stable upon cycling. This work shows that ternary amides containing transition metals have great potential as hydrogen storage materials.

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Decomposition of lithium amide and imide films on nickel

Cited by 8 publications

References 23 publications

Complex Hydrides for Hydrogen Storage

Complex Hydrides for Hydrogen Storage

Effect of Gaseous Impurities on Long-Term Thermal Cycling and Aging Properties of Complex Hydrides for Hydrogen Storage

Ternary Amides Containing Transition Metals for Hydrogen Storage: A Case Study with Alkali Metal Amidozincates

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