Decontamination coupled with dynamic adsorption of sulfur mustard (CEES) and nerve agent-sarin simulants (DMMP) on synthesized zeolite-alpha with its metal oxide composites

Meenu, Km; Tiwari, Kautily Rao; Tomar, Radha; Kumar Gupta, Arvind

doi:10.1080/01932691.2024.2307578

Cited by 2 publications

(1 citation statement)

References 47 publications

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“…[38] Meenu et al have synthesised zeolites based nanocrystalline CrÀ O-Alpha and AgÀ O-Alpha with increase in decontamination potential of CEES and DMMP in 12 h at about 93-98 %. [39] Herein, we report the synthesis of a mixed metal Ce/ ZrÀ UiO-66@LiO t Bu metal-organic framework (MOF) (Scheme 1) which combines the unique characteristics of cerium (Ce) and lithium (Li) inside the UiO-66 framework. The incorporation of cerium into the UiO-66 framework plays a key role, as cerium ions are known for their redox properties and catalytic activity.…”

Section: Introductionmentioning

confidence: 99%

Post‐Synthetic Modification of Mixed‐Metal UiO‐66 Framework for Rapid Neutralization of Chemical Warfare Agent Simulants

Kumar,

Banerjee

2024

ChemistrySelect

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Metal‐organic frameworks (MOFs) are a promising class of materials for catalysis, offering unique opportunities for designing efficient and selective catalysts. In this study, we have focused on the synthesis and catalytic activity of a novel mixed metal MOF, Ce/Zr−UiO‐66@LiOtBu, designed for the rapid hydrolysis of chemical warfare agents simulants: dimethyl 4‐nitrophenyl phosphate (DMNP) and 2‐chloroethyl ethyl sulfide (CEES). This MOF was thoroughly characterized using powder X‐ray diffraction (PXRD), BET surface area, and inductively coupled plasma optical emission spectrometry (ICP‐OES). The catalytic performance of Ce/Zr−UiO‐66@LiOtBu was monitored in the hydrolysis of DMNP and CEES by using 31P NMR and GC‐MS respectively. Remarkably, the MOF demonstrated rapid and efficient catalytic activity, breaking the P−O bond in DMNP with 2 min and the hydrolysis of CEES was observed in less than 45 min The results suggest the potential application of Ce/Zr−UiO‐66@LiOtBu as a robust catalyst in the detoxification of chemical warfare agent simulants. Our findings highlight the novelty of Ce/Zr−UiO‐66@LiOtBu as a catalytically active MOF, showcasing the successful integration of cerium ions and lithium tert‐butoxide to enhance basicity.

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Section: Introductionmentioning

confidence: 99%

Post‐Synthetic Modification of Mixed‐Metal UiO‐66 Framework for Rapid Neutralization of Chemical Warfare Agent Simulants

Kumar,

Banerjee

2024

ChemistrySelect

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Catalysis and decontamination: a versatile tool in the safe and sustainable degradation of chemical warfare agents

Econdi,

Caselli,

Marchesi

et al. 2024

Eur. Phys. J. Plus

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Decontamination is a critical and enabling capability to mitigate and, in the best cases, neutralize the threat of chemical warfare agents (CWAs) to human health and the environment. Well-established conventional decontamination methods will be described and compared to more recent approaches based on catalytic degradation, in the presence of nanostructured catalysts or enzymatic systems, photochemical and photocatalytic abatement and active adsorption on high-performance innovative porous solid materials. Graphical abstract

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Decontamination coupled with dynamic adsorption of sulfur mustard (CEES) and nerve agent-sarin simulants (DMMP) on synthesized zeolite-alpha with its metal oxide composites

Cited by 2 publications

References 47 publications

Post‐Synthetic Modification of Mixed‐Metal UiO‐66 Framework for Rapid Neutralization of Chemical Warfare Agent Simulants

Post‐Synthetic Modification of Mixed‐Metal UiO‐66 Framework for Rapid Neutralization of Chemical Warfare Agent Simulants

Catalysis and decontamination: a versatile tool in the safe and sustainable degradation of chemical warfare agents

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