2005
DOI: 10.1002/ejlt.200401108
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Decreased benzo(a)pyrene concentration in rapeseed oil packed in polyethylene terephtalate

Abstract: Decreased benzo(a)pyrene concentration in rapeseed oil packed in polyethylene terephtalateCommercially available rapeseed oil, the same oil additionally refined physically, and paraffin oil for comparison purposes were spiked with benzo(a)pyrene (BaP) at the level of 29.4, 34.3, and 50.4 mg kg 21, respectively, filled into polyethylene terephtalate (PET) cylindrical-shape receptacles, and the BaP concentrations were followed within 73 h by HPLC analysis. During this time, the BaP concentrations decreased to 22… Show more

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Cited by 7 publications
(3 citation statements)
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“…competed with BaP, and affected the rate of BaP diffusion in the oils and extent of adsorption onto PET. For these reasons, the final state of PAH-PET interactions could be classified such as the surface adsorption [53], what limits considerably the PET capacity in removal processes of PAHs from liquid media.…”
Section: Characterization Of Physicochemical Processes In Petmentioning
confidence: 99%
“…competed with BaP, and affected the rate of BaP diffusion in the oils and extent of adsorption onto PET. For these reasons, the final state of PAH-PET interactions could be classified such as the surface adsorption [53], what limits considerably the PET capacity in removal processes of PAHs from liquid media.…”
Section: Characterization Of Physicochemical Processes In Petmentioning
confidence: 99%
“…which gives rise to almost a pure triacylglycerol mixture formation. The removal of these compounds from rapeseed oil increased the equilibrium coefficient as shown in Table 1 ( ŠIMKO et al 2005). However, the distillation of sunflower oil brought about a considerable decrement of the equilibrium coefficient although the diffusion coefficient had an almost identical value.…”
Section: Resultsmentioning
confidence: 89%
“…This assumption can be supported by the great similarity of the diffusion coefficient values for both sunflower oils (Table 1), which evokes that the main part of BaP interacted with π-electron pairs of linoleic acid, and that only a minor part of BaP interacted with PET. Overall, this "double behaviour" of BaP ŠIMKO et al (2005) resulted in the lowered efficiency of the processes of BaP removal from distilled sunflower oil. Because the removal of BaP is limited by the surface adsorption and the diffusion of BaP into LDPE bulk had been already proven, LDPE was studied for BaP removal from the oil.…”
Section: Resultsmentioning
confidence: 99%