2022
DOI: 10.15826/analitika.2022.26.2.005
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Decreasing the uncertainty of gas chromatographic quantification using the solvent’s signal in the method of external standard

Abstract: Uncertainties of the results of quantitative determinations in gas chromatography using the methods based on the absolute peak areas (including the external standard method) are rather “sensitive” to the reproducibility of injections. The effective way to compensate for such errors is to introduce the additional standards into the samples, followed by replacing the absolute peak areas by their ratios to peak areas of the standards. It is important to underline that any constituents of the samples can be used a… Show more

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