Deep desulphurization of diesel fuels on bifunctional monolithic nanostructured Pt-zeolite catalysts

Ismagilov, Z. R.; Yashnik, S. A.; Startsev, A. N.; Boronin, A. I.; Stadnichenko, A. I.; Kriventsov, V. V.; Kasztelan, S.; Denis, Guillaume; Makkee, Michiel; Moulijn, Jacob A.

doi:10.1016/j.cattod.2009.01.030

Cited by 45 publications

(33 citation statements)

References 50 publications

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…The HDS was accompanied by a significant formation of an intermediate THT. This can be ascribed to hydrogenating character of supported metals at higher hydrogen pressure of 2 MPa [33,34]. It is worth to mention that THT amount was substantially lower on the catalysts of PdA-PtO series, giving a highest selectivity in desulfurized products, C 4 hydrocarbons.…”

Section: Activity In Hds Of Thiophene and Benzothiophenementioning

confidence: 93%

Effect of catalyst precursor and its pretreatment on the amount of β-Pd hydride phase and HDS activity of Pd-Pt/silica-alumina

Vı́t

Gulková

Kaluža

et al. 2014

Applied Catalysis B: Environmental

View full text Add to dashboard Cite

Section: Activity In Hds Of Thiophene and Benzothiophenementioning

confidence: 93%

Effect of catalyst precursor and its pretreatment on the amount of β-Pd hydride phase and HDS activity of Pd-Pt/silica-alumina

Vı́t

Gulková

Kaluža

et al. 2014

Applied Catalysis B: Environmental

View full text Add to dashboard Cite

“…[28] The Pt-Cl-400 sample shows very small Pt particles with an average size of about 0.6 nm ( Figure 4). [43][44][45] For the Pt-Cl-400 sample the E b (Pt4f 7/2 ) value for Pt 4 + -like component is a bit higher -74.9 eV. Treatment with H 2 at 250°C causes a negligible increase of the average particle size up to 0.8 nm with the preservation of highly dispersed Pt species.…”

Section: Structural Characterizationmentioning

confidence: 94%

Insight into the Nature of Active Species of Pt/Al₂O₃ Catalysts for low Temperature NH₃ Oxidation

et al. 2019

Self Cite

View full text Add to dashboard Cite

Two series of Pt/γ-Al 2 O 3 catalysts for low temperature NH 3 oxidation were prepared using Pt(NO 3 ) 4 and H 2 PtCl 6 precursors. Using both precursors results in the formation of small Pt particles (d < 1.5 nm), however, Cl-containing Pt precursors give a higher fraction of highly dispersed Pt species. Such species show high stability against thermal or H 2 treatment probably due to the presence of a substantial amount of chlorine on the surface. Treatment of the samples prepared from Pt(NO 3 ) 4 with H 2 leads to the formation of metallic Pt nanoparticles accompanied by the improvement of catalytic activity in NH 3 oxidation at T < 200°C. The main products of ammonia oxidation at temperatures below 250°C were molecular nitrogen and nitrous oxide with the N 2 selectivity reaching 80 %. Operando XANES/ EXAFS revealed that even after H 2 pretreatment at least 40 % of Pt surface remains in oxidized state under reaction conditions resulting in the appearance of N 2 O as a by-product.

show abstract

“…The existing methods of catalytic purification of flue gases from nitrogen oxides are based on NOx reduction by the following reducing agents: ammonia, hydrocarbons, carbon monoxide, etc. [15][16][17]. The literature analysis shows that the most promising catalytic systems are individual or mixed transition metal oxides.…”

Section: The Technology Used Equipment Results Of Testsmentioning

confidence: 99%

Development of Efficient Technologies for Abatement of Nitrogen and Sulfur Oxides in Flues Gases of Coal Combustion

Murko¹,

Khyamyalyaynen²,

Mikhaylova³

et al. 2018

Proceedings of the 9th China-Russia Symposium “Coal in the 21st Century: Mining, Intelligent Equipment and Environment Protecti

View full text Add to dashboard Cite

show abstract

Deep desulphurization of diesel fuels on bifunctional monolithic nanostructured Pt-zeolite catalysts

Cited by 45 publications

References 50 publications

Effect of catalyst precursor and its pretreatment on the amount of β-Pd hydride phase and HDS activity of Pd-Pt/silica-alumina

Effect of catalyst precursor and its pretreatment on the amount of β-Pd hydride phase and HDS activity of Pd-Pt/silica-alumina

Insight into the Nature of Active Species of Pt/Al₂O₃ Catalysts for low Temperature NH₃ Oxidation

Development of Efficient Technologies for Abatement of Nitrogen and Sulfur Oxides in Flues Gases of Coal Combustion

Contact Info

Product

Resources

About

Deep desulphurization of diesel fuels on bifunctional monolithic nanostructured Pt-zeolite catalysts

Cited by 45 publications

References 50 publications

Effect of catalyst precursor and its pretreatment on the amount of β-Pd hydride phase and HDS activity of Pd-Pt/silica-alumina

Effect of catalyst precursor and its pretreatment on the amount of β-Pd hydride phase and HDS activity of Pd-Pt/silica-alumina

Insight into the Nature of Active Species of Pt/Al2O3 Catalysts for low Temperature NH3 Oxidation

Development of Efficient Technologies for Abatement of Nitrogen and Sulfur Oxides in Flues Gases of Coal Combustion

Contact Info

Product

Resources

About

Insight into the Nature of Active Species of Pt/Al₂O₃ Catalysts for low Temperature NH₃ Oxidation