Deep eutectic solvents as functional additives for starch based plastics

Leroy, Éric; DeCaen, Paul G.; Jacquet, Pierre; Coativy, Gildas; Pontoire, Bruno; Réguerre, Anne-Laure; Lourdin, Denis

doi:10.1039/c2gc36107h

Cited by 97 publications

(60 citation statements)

References 17 publications

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“…Over the last two decades novel plasticizers from a group of materials named deep eutectic solvents, or low temperature transition mixtures, have been tested as polysaccharide plasticizing agents (Abbott, Ballantyne, Conde, Ryder & Wise, 2012;Leroy et al, 2012;Ramesh, Shanti & Morris, 2012;Zdanowicz & Spychaj, 2011). Deep eutectic solvents (DES) are mixtures of two or more components where the melting temperature of the mixture is much lower than the melting temperature (T m ) of the individual components.…”

Section: Introductionmentioning

confidence: 99%

“…Mainly CC:U (Abbott et al, 2012;Leroy et al, 2012;Ramesh, Shanti & Morris, 2012;Zdanowicz et al, 2011); CC:glycerol (Leroy et al, 2012) and CC:carboxylic acids mixtures (Zdanowicz et al, 2011) have been tested as plasticizers for unmodified starch. Very recently, imidazole-based DESs were studied as starch plasticizers or solvents (Zdanowicz, Spychaj & Mąka, 2016).…”

Section: Introductionmentioning

confidence: 99%

“…Very recently, imidazole-based DESs were studied as starch plasticizers or solvents (Zdanowicz, Spychaj & Mąka, 2016). Most of these reports are related to unmodified corn starch films performed via extrusion (Leroy et al, 2012), melt processing (Abbott et al, 2012) or casting method (Ramesh et al, 2012).…”

Section: Introductionmentioning

confidence: 99%

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Mechanical and barrier properties of starch-based films plasticized with two- or three component deep eutectic solvents

Zdanowicz

Johansson

2016

Carbohydrate Polymers

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Mechanical and barrier properties of starch-based films plasticized with two- or three component deep eutectic solvents

Zdanowicz

Johansson

2016

Carbohydrate Polymers

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“…Rimsza and Corrales (2010) used ChClbased DESs as agents for surface contaminant cleaning to selectively remove CuO from a silicon dioxide surface [11]. ChCl-based DES was also used as functional additives for starch based plastics [12]. Also, DESs were employed as catalysts for biodiesel production from industrial low-grade crude palm oil [13,14].…”

Section: Introductionmentioning

confidence: 99%

Triethylene glycol based deep eutectic solvents and their physical properties

Hayyan

Aissaoui

Hashim

et al. 2015

Journal of the Taiwan Institute of Chemical Engineers

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a b s t r a c tDeep eutectic solvents (DESs) have been recently emerged as new ionic liquids (ILs) analogues. The low vapor pressure, inflammability, biodegradability and positive effect on the environment make DESs more favorable as neoteric solvents. In this study, triethylene glycol (TEG) was selected as a hydrogen bond donor (HBD) to form DESs with five types of phosphonium and ammonium salts, namely methyltriphenylphosphonium bromide (MTPB), benzyltriphenylphosphonium chloride (BTPC), allyltriphenylphosphonium bromide (ATPB), choline chloride (2-hydroxyethyl-trimethylammonium) (ChCl) and N,N-diethylenethanolammonium chloride (DAC). The physical properties of the synthesized DESs were measured such as freezing point, viscosity, electrical conductivity, Walden rule, density, pH and water content. In addition, the Fourier transform infrared spectroscopy (FTIR) was employed to study the functional groups. The experiments were conducted at different temperatures, i.e. 25-80°C. It was found that DESs have suitable properties to be used in industrial processes such as separation, extraction, biochemical, petroleum and gas technology.

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“…A recent study by Leroy et al has presented similar data for starch/zein protein blends and shown the longterm stability of these materials. 23 In the current study we attempt to make fibreboard using thermoplastic starch as the binder matrix.…”

Section: Introductionmentioning

confidence: 99%

Starch as a replacement for urea-formaldehyde in medium density fibreboard

et al. 2012

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Medium density fibreboard (MDF) is a ubiquitous product formed from wood flour and a formaldehydebased resin. The use of the latter component causes some health and environmental concerns and its use is restricted. The current study shows that thermoplastic starch can be used in place of the thermoset resin to produce materials of similar mechanical strength but with clear environmental benefits. All of the components are compostable and the resin being a thermoplastic allows the potential for remoulding and recycling which has clear environmental impact benefits.

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Deep eutectic solvents as functional additives for starch based plastics

Cited by 97 publications

References 17 publications

Mechanical and barrier properties of starch-based films plasticized with two- or three component deep eutectic solvents

Mechanical and barrier properties of starch-based films plasticized with two- or three component deep eutectic solvents

Triethylene glycol based deep eutectic solvents and their physical properties

Starch as a replacement for urea-formaldehyde in medium density fibreboard

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