Deep eutectic solvents on a tightrope: balancing the entropy and enthalpy of mixing

van den Bruinhorst, Adriaan; Corsini, Chiara; Depraetère, Guillaume; Cam, Nithavong; Pádua, Agílio; Costa Gomes, Margarida

doi:10.1039/d4fd00048j

Faraday Discuss.

2024

DOI: 10.1039/d4fd00048j

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Deep eutectic solvents on a tightrope: balancing the entropy and enthalpy of mixing

Adriaan van den Bruinhorst,

Chiara Corsini,

Guillaume Depraetère

et al.

Abstract: The large melting point depressions characterising deep eutectic solvents (DESs) are related to negative deviations from ideal mixing behaviour characterised by the excess Gibbs energy. Favourable excess Gibbs energies result...

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2025

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Interplay of aprotic ionic liquids with hydrogen bonded networks in associating aliphatic alcohols

Červinka

2025

Journal of Molecular Liquids

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On the composition and isomerism effect in the thermal and structural properties of choline chloride/hydroxyphenol deep eutectic solvents

Casu,

Busato,

Palluzzi

et al. 2024

Phys. Chem. Chem. Phys.

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Good vibrations: understanding deep eutectic solvents through the lens of vibrational spectroscopy

Araújo,

Abranches,

Coutinho

et al. 2024

Applied Spectroscopy Reviews

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Deep eutectic solvents on a tightrope: balancing the entropy and enthalpy of mixing

Abstract: The large melting point depressions characterising deep eutectic solvents (DESs) are related to negative deviations from ideal mixing behaviour characterised by the excess Gibbs energy. Favourable excess Gibbs energies result...

Cited by 3 publications

References 37 publications

Interplay of aprotic ionic liquids with hydrogen bonded networks in associating aliphatic alcohols

Interplay of aprotic ionic liquids with hydrogen bonded networks in associating aliphatic alcohols

On the composition and isomerism effect in the thermal and structural properties of choline chloride/hydroxyphenol deep eutectic solvents

Good vibrations: understanding deep eutectic solvents through the lens of vibrational spectroscopy

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