We have observed the diffuse X-ray emission from the Galactic center (GC) using the X-ray Imaging Spectrometer (XIS) on Suzaku. The high-energy resolution and the low-background orbit provide excellent spectra of the GC diffuse X-rays (GCDX). The XIS found many emission lines in the GCDX near the energy of K-shell transitions of iron and nickel. The most pronounced features are Fe I Kα at 6.4 keV and K-shell absorption edge at 7.1 keV, which are from neutral and/or low ionization states of iron, and the K-shell lines at 6.7 keV and 6.9 keV from He-like (Fe XXV Kα) and hydrogenic (Fe XXVI Lyα) ions of iron. In addition, Kα lines from neutral or low ionization nickel (Ni I Kα) and He-like nickel (Ni XXVII Kα), and