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Lattice parameters in tl.e mixed aluminate sodalite system (Ca, -xSrx)8 [A1,,0,,] (CrO,), have been determined on the Aachen/Frankfurt (Darmstadt)/Tubingen powder diffractometer at DESY/ Hasylab, Hamburg, FRG, wi:h synchrotron radiatio.1 (SR) of a wavelength of I = 1.383 A. From these data the values of the spontaneous strain for tetragoqal and orthorhombic samples were calculated. The synchrotron data were compared with those obtained by using a conventional Guinier camera with sealed tube CuKcr, X-rays. In the mixed system a concentration range A x of abcut 4 mol%, i.e. in the composition range x from 0.23 to 0.27, exists, in which the conventional technique still indicates cubic symmetry, whereas synchrotron data clearly exhibit tetragonal peak splitting. In order to determine the phase diagrams of mixed aluminate sodalites -or of comparable systems -and to interpret the physical properties of the phases correctly, sealed tube X-rays are of limited value. Availability of SR beamtime is a crucial factor in the experiments.
Lattice parameters in tl.e mixed aluminate sodalite system (Ca, -xSrx)8 [A1,,0,,] (CrO,), have been determined on the Aachen/Frankfurt (Darmstadt)/Tubingen powder diffractometer at DESY/ Hasylab, Hamburg, FRG, wi:h synchrotron radiatio.1 (SR) of a wavelength of I = 1.383 A. From these data the values of the spontaneous strain for tetragoqal and orthorhombic samples were calculated. The synchrotron data were compared with those obtained by using a conventional Guinier camera with sealed tube CuKcr, X-rays. In the mixed system a concentration range A x of abcut 4 mol%, i.e. in the composition range x from 0.23 to 0.27, exists, in which the conventional technique still indicates cubic symmetry, whereas synchrotron data clearly exhibit tetragonal peak splitting. In order to determine the phase diagrams of mixed aluminate sodalites -or of comparable systems -and to interpret the physical properties of the phases correctly, sealed tube X-rays are of limited value. Availability of SR beamtime is a crucial factor in the experiments.
We report results of a Raman study on single crystals of 16 boracites M3B7O13X (M = Cr,Co,Ni,Cu,Zn,Cd; X = Cl,Br,I) over a broad temperature range. The Raman modes for all boracites in their high‐temperature prototype cubic (Fbold-italic4true¯3c) phase are compared. With decreasing temperature, most (but not all) compounds present a transition to the low‐temperature orthorhombic phase (Pca21) or to a sequence of orthorhombic, monoclinic (Pa), and trigonal (R3c) phases. The variations of the Raman spectra through different phases are studied in detail. Special attention is paid to the temperature hysteresis near the transitions and the dependence of transition temperature on the direction of crystal growth for the same material. Copyright © 2014 John Wiley & Sons, Ltd.
Elect,ron diffraction and microscopy observations rcveal that t,lic sequence of t h e phnsc trailsformtitions of Cuz -,Te (.-< 0.05) is a typiciLl case of a riormal-incommcnstlritte-commeris~~r~~t~~ phasc tmnsition, with the incommensurtite phase split,ted into two phases ; oiio of these, t hv yphasc, is modulated by regularly spaced discommensurations, whereas t,iie second one, P-phast,. is clu"si-commcnsur~ite wit,h H number of disconimensur;ltioris pinned by defects in the crystal. At Imst five commensurate phases (qI-phasc) of different periods are found st room tcmpcrtit,rtr.c.. The domain structurc of the incommensnratc phases is ;dso a,nalyzed. Piwticiilarly tho forniation mechanism of XPB's in the y-phase, exhibiting two well defined crystallogrsphic orirntat,ions, is dimlosed by dynaiiiic observations of the S + y phme transformation.Iclektronenbeugung und mikroskopische Reobachtungen zeigen, dnl3 die Folge der Phasentransformationcn vori Cuz -,Te (x < 0,05) einen typischcn Fa,ll eines normalen Plxrseniibergangs inkonimensurilbcl-l;onimcnsurabel dsrst,ellt, wobei die inkommensurable Phase in zwei Phasen anfgrspaltcn ist; einc von diesen, die y-Phase, wird durch raumlicli regullir angeordnete UrinieBbarkeiten moduliert, wahrend die zweite, die P-Phase, quasi-kornmensur~~bel ist, mit einer Anzahl von UnmeUb;wkeiten, die dnrch Defekte im Kristall fostgelialten werden. Wenigst,eris fiinf kommensurable Phitseri (rII-Phase) mit iinterschicdlichen Perioden werdcn bei Zimmertemperat u r gefunden. Die Domkenstruktnr der inkommensurablen Phasen wird ebenfalls andysiert. Speziell der Bildungsmechanismns der APB's in der y-Phase, die zwei gut definierte kristallographische Ricl~t~ungen zcigon, wird durch dynamische Beobnchtungeri des 6 y-Phaseniibergangs aufgedeckt.
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