optoelectronic devices, [6][7][8] chirality, [9,10] magnetism, [11][12][13] and surface-enhanced Raman spectroscopy. [14][15][16] Controlling the structure of an environment is known to impact on photophysical properties of semiconductors. The effects can be revealed through alterations of energy and charge transfers, [17][18][19] spectral shifts and amplitude variation of both absorption and transmission, [20][21][22][23] as well as polarization, [24] and emission amplitude. [25][26][27][28] In this context, engineering spontaneous emission rate with elaborated nanostructures is of particular interest and the effect of various structures has been explored including confinement, [28][29][30] plain metal films and metal