In this paper, we introduce the notion of the Hom-Leibniz-Rinehart algebra as an algebraic analogue of Hom-Leibniz algebroid, and prove that such an arbitrary split regular Hom-Leibniz-Rinehart algebra L is of the form L = U + γ I γ with U a subspace of a maximal abelian subalgebra H and any I γ , a well described ideal of L, satisfyingIn the sequel, we develop techniques of connections of roots and weights for split Hom-Leibniz-Rinehart algebras respectively. Finally, we study the structures of tight split regular Hom-Leibniz-Rinehart algebras.