Time dependent dielectric breakdown (TDDB) measurements have been made on a 96 A oxide deposited by remote plasma enhanced chemical vapor deposition (RPECVD) upon a 300~ St(100) device grade substrate. The oxide was used to form an array of I0 • i0 ~m square capacitors. The oxide was then subjected to electron injection from the substrate at 0.1 A/cm 2 constant stress current. The charge-to-breakdown (QBD) was measured and found to be 39 +-3 C/cm 2. A similarly fabricated 92 A thermal oxide capacitor array showed a QBD value of 49 _+ 4 C/cm 2. Analysis of the forcing voltage during stress showed the RPECVD oxide to have an initial trap density of i. 76 • 0.07 • 1018 em -3, compared to 5.6 _+ 0.2 • i017 cm ~ for the thermal oxide. In both cases, at 0.i A/era 2, the stress voltage across the oxide rose linearly with time. 16 3 1 4-16 3 1Trap generation rates of 3.1 + 0.2 X 10 cm-s-and 2.0 _ 0.2 • 10 cm-s-were measured for the RPECVD and thermal oxides, respectively. The TDDB data were analyzed to find breakdown occurring in localized areas of (68 + 11 ~)2 containing 18 + 3 filled electron traps.