Degradation of antiviral drug acyclovir by thermal activated persulfate process: Kinetics study and modeling

Chunsheng, Ding; Cai, Zhiyue; Hu, Chenkai; Lei, Jia; Wang, Lei; Li, Qingsong; Li, Xueyan; Deng, Jing

doi:10.1016/j.chemosphere.2023.138247

Cited by 14 publications

(3 citation statements)

References 42 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The gas temperature was 350 °C, the flow rate of dry gas (N 2 ) was 121 min −1 , and the capillary voltage was 4000 V. The mass spectra were obtained in the range of 100 ∼ 1500 m/z. 35 One way to calculate the electrical energy per order (EE/O) is by utilizing the following formula: 36…”

Section: Methodsmentioning

confidence: 99%

Electrocatalytic Degradation of Acyclovir by Three-Dimensional Porous Lead Dioxide Anodes: Condition Optimization, Kinetic Analysis and Degradation Mechanisms

Wei,

Wang,

Chen

et al. 2024

J. Electrochem. Soc.

View full text Add to dashboard Cite

A three-dimensional porous lead dioxide electrode (3D-PbO2) was developed by the template electrodeposition approach. Polystyrene microspheres were prepared by microemulsion polymerization, and then the polystyrene template was loaded on the PbO2 electrode by electrodeposition. Finally, a porous structure was formed by removing the template. Under these optimized conditions, the degradation of acyclovir could achieve complete removal, while the removal of COD was 29.59%. The electrochemical degradation process of acyclovir was consistent with the proposed primary reaction kinetics. The 3D-PbO2 electrode was comprehensively characterized using scanning electron microscopy S(EM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) techniques. The SEM analysis revealed the presence of well-defined porous structures on the electrode surface, while the XRD results indicated a reduction in electrode crystal sizes. Additionally, the XPS analysis demonstrated a higher proportion of reactive oxygen species on the 3D-PbO2 electrode. The electrochemical properties of the electrode were investigated using CV and EIS. The experimental findings demonstrate that the 3D-PbO2 electrode exhibits a higher oxygen evolution potential and lower charge transfer resistance than the conventional PbO2 electrode. This study presents a viable approach to enhance the electrochemical oxidation performance of lead dioxide.

show abstract

Section: Methodsmentioning

confidence: 99%

Electrocatalytic Degradation of Acyclovir by Three-Dimensional Porous Lead Dioxide Anodes: Condition Optimization, Kinetic Analysis and Degradation Mechanisms

Wei,

Wang,

Chen

et al. 2024

J. Electrochem. Soc.

View full text Add to dashboard Cite

show abstract

“…Second-order reaction rate constants of ROS with different contaminants; n is the number of second-order rates. Data obtained from ref. ,,− …”

Section: Overview Of Ac Regeneration Methods Via Aopsmentioning

confidence: 99%

Advanced Oxidation Processes for Activated Carbon Regeneration: From Fundamental to Application

Liu,

Chen,

et al. 2024

ACS EST Water

View full text Add to dashboard Cite

Activated carbon (AC) is a cornerstone in water treatment technologies and is renowned for its robust ability to eliminate a wide range of contaminants. However, the adsorption capability of AC diminishes over time and eventually reaches saturation. Given environmental and economic considerations, the regeneration of spent AC emerges as a preferable option. Advanced oxidation processes (AOPs) have been considered a promising approach for spent AC regeneration due to their high efficiency in degrading organic pollutants. This review provides an overview of established AOPs technologies for AC regeneration, elucidating their regeneration mechanisms and key influencing factors. A critical comparison of physicochemical transformations in postregeneration AC and the regeneration efficiency through various AOPs technologies is presented. Moreover, the review addresses some common overlooks in AC regeneration experimental designs and explores the scalability of AOPs regeneration technologies. Finally, future research directions were suggested to improve the AOPs-based regeneration technologies.

show abstract

“…12 When the PS was activated, sulfate radicals (SO 4 • − ), a green oxidant with a higher redox potential (E 0 = 2.5-3.1 V), a larger range of operational pH, and better selectivity were generated, compared to traditional •OH. [13][14][15] However, external activation energy is generally required to activate SO 4 • − , such as heat, light, electricity, or microwaves, [16][17][18][19][20] leading to excessive energy consumption during the treatment process. It seems that the requirements for selecting more suitable alternative catalysts are becoming increasingly urgent.…”

Section: Introductionmentioning

confidence: 99%

The performance and mechanism of persulfate activated by CuFe-LDHs for ofloxacin degradation in water

Zhang,

et al. 2024

Environ. Sci.: Nano

View full text Add to dashboard Cite

show abstract

Degradation of antiviral drug acyclovir by thermal activated persulfate process: Kinetics study and modeling

Cited by 14 publications

References 42 publications

Electrocatalytic Degradation of Acyclovir by Three-Dimensional Porous Lead Dioxide Anodes: Condition Optimization, Kinetic Analysis and Degradation Mechanisms

Electrocatalytic Degradation of Acyclovir by Three-Dimensional Porous Lead Dioxide Anodes: Condition Optimization, Kinetic Analysis and Degradation Mechanisms

Advanced Oxidation Processes for Activated Carbon Regeneration: From Fundamental to Application

The performance and mechanism of persulfate activated by CuFe-LDHs for ofloxacin degradation in water

Contact Info

Product

Resources

About