Degradation of Remazol Black dye from Aqueous Solution by Heterogeneous NH3(MoO3)3/H2O2 System

Abstract

Aims: The pollution of the environment by organic dyes in water is a matter of great concern. Wastewater containing dyes is difficult to treat by conventional wastewater treatment methods such as coagulation, ozonation, biological treatment, etc. This is why the implementation of an effective method by not generating pollutants secondary is necessary.
 The objective of this work is to study the degradation of remazol black, an azo dye, by the coupling of hydrogen peroxide - molybdenum oxide nanoparticle. The nanoparticles were synthesized by the aqueous sol-gel method using a reflux assembly.
 Study Design: Random design.
 Methodology: The nanoparticles were synthesized by the aqueous sol-gel method using a reflux assembly and then characterized by X-ray diffraction and using software origin to determine the particles size by Scherrer's formula. The influence of hydrogen peroxide, molybdenum oxide and hydrogen peroxide / molybdenum oxide coupling, and the degradation kinetics of remazol black were studied. We also studied the influence of the pH of the solution, the mass of molybdenum nanoparticles and the concentration of remazol black on the dye degradation process.
 Results: The results showed that the synthesized oxide is ammonium molybdenum trioxide NH3(MoO3)3) with a hexagonal structure and size 22.79 nm. The study of the catalytic effect revealed a degradation rate of 17%, 0.83% and 42% respectively for H2O2, NH3(MoO3)3 and the coupling NH3(MoO3)3/H2O2. The study also showed that the degradation of remazol black by the couple NH3(MoO3)3 /H2O2 is better at pH = 4 and for a mass of nanoparticles of 400 mg. This degradation kinetics are pseudo 1st order. In addition, the degradation rate decreases when the concentration of remazol black increases. The efficiency of the coupling (NH3(MoO3)3 / H2O2 showed at ambient temperature, that it was possible to remove about 60% of the initial color of remazol black from the water in a batch reaction.
 Conclusion: The reflux method makes it possible to synthesize molybdenum nanoparticles. The molybdenum oxide hetero-Fenton process is effective in removing remazol black dye from water.