Degradation of Remazol Brilliant Blue Dye Using Persulfate Activated by Fe₃O₄@PDA Nanoparticles: Kinetic Studies, Radical Determination, and Phytotoxicity Test

Abstract

In the current research work, an advanced oxidation process was applied to the degradation of Remazol brilliant blue dye (RBBD) using a sulfate radical. Fe 3 O 4 @PDA nanoparticles were synthesized using coprecipitation and self-polymerization techniques. Nanoparticle formation was confirmed by XRD, FTIR, FESEM-EDX, VSM, and XPS analyses. The crystalline nature of the material showed that it possessed a spherical shape with an M s value of 58 emu/g. The elemental composition and binding energy from EDX and XPS analyses showed successful doping. Batch studies were conducted, and experimental studies showed that the optimum condition for degradation of 90 ppm of RBBD was 0.3 g/ L of nanomaterial, 20 mM PS at pH 3, achieving 91.35% degradation. The kinetic model suitable for this study was a pseudo-second-order kinetic model with R 2 value >0.9. From the radical identification tests, sulfate radicals played a dominant role in degradation, and to confirm it, EPR analysis was conducted using DMPO. A stability test was performed for 5 cycles in which the degradation efficiency was reduced appreciably. From XPS, XRD, and EDX analyses, the elemental composition and oxidation state of the recycled material used in the fifth cycle showed variation in a negligible manner when compared to the fresh catalyst used in the first cycle of the degradation experiment. Intermediate identification was done by GCMS analysis, and it disclosed the formation of aliphatic products from the degradation of RBBD with less toxicity. Phytotoxicity analysis was conducted using green grams for 10 days, and it proved that intermediates formed in the solution were nontoxic to the plants. Additionally, TOC and COD removal % were attained to be 80.021 and 80.903%, respectively, which confirm the mineralization efficacy. Hence, this research work proved the efficient performance of the catalyst for RBBD degradation with less formation of intermediates, and therefore, this technique is most suitable for the reduction of water pollution.