Degradation of rhodamine B photocatalyzed by hydrothermally prepared Pd-doped Bi2MoO6 nanoplates

Simultaneous Pd Nanoparticle Deposition and Enhancement in the Surface Oxygen Vacancy of Bi2MoO6 Nanoflakes for Room Temperature Vanillin Hydrodeoxygenation

“…This result is consistent with the PXRD results for the formation of the pure Bi 2 MoO 6 phase. In Raman spectra, the BMO strong band at 799 cm –1 is attributed to the A 1g mode of Mo–O stretching vibrations of the MoO 6 octahedron. , The peaks at 718 and 844 cm –1 were also assigned to the A 1g mode and correspond to the asymmetric and symmetric vibrations of the MoO 6 octahedron, respectively. , Raman peaks in the wavenumber range of 200–400 cm –1 can be assigned to the symmetric stretching vibrations of the Mo–O bonding mode, and Raman peaks below 200 cm –1 are attributed to the translation of molybdenum and bismuth atoms. , After Pd loading over BMO, no significant shift or any additional peak was evolved in the Raman spectra of Pd/BMO samples which indicates that the crystal structure of BMO was retained during the loading of Pd nanoparticles. However, a significant decrease in the intensities of the peaks at 146, 194, 287, 348, 718, 799, and 844 cm –1 was observed for all Pd-supported samples.…”

“…52,53 Raman peaks in the wavenumber range of 200−400 cm −1 can be assigned to the symmetric stretching vibrations of the Mo−O bonding mode, and Raman peaks below 200 cm −1 are attributed to the translation of molybdenum and bismuth atoms. 52,53 After Pd loading over BMO, no significant shift or any additional peak was evolved in the Raman spectra of Pd/BMO samples which indicates that the crystal structure of BMO was retained during the loading of Pd nanoparticles. However, a significant decrease in the intensities of the peaks at 146, 194, 287, 348, 718, 799, and 844 cm −1 was observed for all Pd-supported samples.…”

“…In Raman spectra, the BMO strong band at 799 cm −1 is attributed to the A 1g mode of Mo−O stretching vibrations of the MoO 6 octahedron. 52,53 The peaks at 718 and 844 cm −1 were also assigned to the A 1g mode and correspond to the asymmetric and symmetric vibrations of the MoO 6 octahedron, respectively. 52,53 Raman peaks in the wavenumber range of 200−400 cm −1 can be assigned to the symmetric stretching vibrations of the Mo−O bonding mode, and Raman peaks below 200 cm −1 are attributed to the translation of molybdenum and bismuth atoms.…”

“…52,53 The peaks at 718 and 844 cm −1 were also assigned to the A 1g mode and correspond to the asymmetric and symmetric vibrations of the MoO 6 octahedron, respectively. 52,53 Raman peaks in the wavenumber range of 200−400 cm −1 can be assigned to the symmetric stretching vibrations of the Mo−O bonding mode, and Raman peaks below 200 cm −1 are attributed to the translation of molybdenum and bismuth atoms. 52,53 After Pd loading over BMO, no significant shift or any additional peak was evolved in the Raman spectra of Pd/BMO samples which indicates that the crystal structure of BMO was retained during the loading of Pd nanoparticles.…”

Pd Nanoparticle-Decorated Bi2MoO6 Nanoflakes with Surface Oxygen Vacancies for Selective Room-Temperature Furfural Hydrogenation and Benzyl Phenyl Ether Hydrogenolysis

“…In the Raman profile of these samples, the strong band at 799 cm −1 is ascribed to the A 1g mode of Mo−O stretching vibrations of the MoO 6 octahedron. 44,45 The asymmetric and symmetric vibrations of the MoO 6 octahedron are shown by the peaks at 718 and 844 cm −1 , which were both attributed to the A 1g mode. 44,45 Mo−O bonding mode's symmetric stretching vibrations can be attributed to Raman peaks in the wave-number range of 200−400 cm −1 , while molybdenum and bismuth atom translation was the cause of Raman peaks below 200 cm −1 .…”