Neutrons are analyzed
in various fields such as space exploration,
neutron radiography, and medicine. When neutrons are employed, a neutron
detector is required to control the exposure dose. However, issues
such as detector radiation tolerance, response linearity, and γ-ray
noise limit the development of effective neutron detectors. Metal
halide perovskite based direct conversion radiation detectors exhibit
attractive characteristics such as being solution-processable at low
temperatures and possessing tunable band gaps, low trap density, high
charge carrier mobility, high radiation tolerance, and fast responses.
The perovskite device’s potential for high-flux neutron applications
has not been greatly determined; however, only related research has
been conducted thus far. Here, we demonstrate a hybrid organic–inorganic
perovskite semiconductor based neutron detector that satisfies all
high-flux neutron detection requirements. The perovskite device was
designed to possess a structure similar to that of solar cells and
could be driven solely by the built-in potential, without an applied
voltage. Using this perovskite device, a neutron detector was designed
to maximize the efficiency of the back side conversion configuration
and minimize sensitivity variations. Experiments on irradiation with
the spectrum neutrons and calculations of the reaction rates revealed
a 25 meV neutron sensitivity of 6.0 × 10–17 A n–1 cm–2 and a detection limit
of 106 n cm–2 s–1.
Further, an optical response test showed that a dynamic detection
range with 6–7 orders of magnitude was realized. The detection
characteristics for high-flux neutrons indicated a stable operation
with no degradation during neutron irradiation at a fluence of −1012 cm–2. Moreover, noise from γ-rays
had an insignificant effect on the accuracy of the neutron flux measurements.
These results highlight that the proposed neutron detector based on
a perovskite solar cell is a suitable monitoring sensor for high-flux
neutrons.