Vegetable oil extraction, as performed today by the oilseed-crushing industry, usually involves solvent extraction with commercial hexane. After this step, the vegetable oil-hexane mixture (miscella) must be treated to separate its components by distillation. If solvent-resistant membranes with good permeation properties can be obtained, membrane separation may replace, or be used in combination with, conventional evaporation. Two tailormade flat composite membranes, poly(vinylidene fluoride) (PVDF-Si and PVDF-CA) and a commercially available composite membrane (MPF-50), were used to separate a crude sunflower oil-hexane mixture. The effects of temperature, cross-flow velocity (v), transmembrane pressure (Dp), and feed oil concentration (C f ) on membrane selectivity and permeation flux were determined. The PVDF-Si membrane achieved the best results, being stable in commercial hexane and having promising permselectivity properties for separation of vegetable oil-hexane miscella. Improved separation performance was obtained at C f = 25%, Dp = 7.8 bar, T = 30°C, and v = 0.8 m s -1 ; a limiting permeate flux of 12 Lm -2 h -1 and 46.2% oil retention were achieved. Low membrane fouling was observed under all the experimental conditions studied.