2015
DOI: 10.1016/j.apcata.2015.06.035
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Dehydroaromatization of methane over Sn–Pt modified Mo/H-ZSM-5 zeolite catalysts: Effect of preparation method

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Cited by 23 publications
(10 citation statements)
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“…At 973 K, addition of 0.1 wt % Sn to the Pt-Mo/H-ZSM-5 catalyst yielded slightly lower methane conversion while decreasing the extent of coke deposition and increasing the selectivity to aromatics. Catalysts prepared by sequential impregnation of Pt followed by Sn exhibited higher benzene selectivity and better coke mitigation in comparison to catalysts prepared by coimpregnation. , …”
Section: Introductionmentioning
confidence: 94%
“…At 973 K, addition of 0.1 wt % Sn to the Pt-Mo/H-ZSM-5 catalyst yielded slightly lower methane conversion while decreasing the extent of coke deposition and increasing the selectivity to aromatics. Catalysts prepared by sequential impregnation of Pt followed by Sn exhibited higher benzene selectivity and better coke mitigation in comparison to catalysts prepared by coimpregnation. , …”
Section: Introductionmentioning
confidence: 94%
“…It was suggested that ZSM-5 zeolite was one of the most suitable supports, and molybdenum was the proper metal component . A variety of synthesis techniques and promoters were applied to improve the overall catalytic performance in conventional fixed-bed reactors. Various catalysts have been developed through modification of the structural feature of the zeolite supports, adjusting metal species and acidity with the intention of enhancing the catalytic activity, stability, and selectivity to aromatics. …”
Section: Development Of Catalysts For Mdamentioning
confidence: 99%
“…Moreover, the coke deposit reduced from 30% to 15% at 0.05 wt % of Sn. Furthermore, they synthesized platinum and tin species modified Mo/HZSM-5 zeolite catalysts for MDA . It was concluded that the catalytic performances of catalysts with additional tin led to lower methane conversion but higher aromatic products selectivity.…”
Section: Development Of Catalysts For Mdamentioning
confidence: 99%
“…Mo/W oxide supported on ZSM-5/MCM-22 is a well-studied bifunctional catalyst for methane dehydroaromatization [2,25]. It has been reported that the metal carbide species produced from Mo/W oxides activate methane by forming CH x species, which is dimerized into C 2 H y species [13,26]. Previously, this group demonstrated high activity and strong aromatic selectivity for methane dehydroaromatization (MDHA) using Mo oxide doped on sulfated zirconia (SZ) solid acid catalysts [15].…”
Section: Introductionmentioning
confidence: 99%