2016
DOI: 10.1039/c5cy01912e
|View full text |Cite
|
Sign up to set email alerts
|

Dehydrogenative coupling of alcohols and carboxylic acids with hydrosilanes catalyzed by a salen–Mn(v) complex

Abstract: A manganese–salen complex is shown to be effective in catalyzing the dehydrogenative coupling of hydroxyl groups with hydrosilane.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1
1
1
1

Citation Types

0
28
0

Year Published

2016
2016
2020
2020

Publication Types

Select...
7
1

Relationship

0
8

Authors

Journals

citations
Cited by 38 publications
(28 citation statements)
references
References 56 publications
0
28
0
Order By: Relevance
“…Over the years, direct dehydrogenative coupling of alcohols with hydrosilanes emerged as a green, halogen-free alternative to the former approach. At the moment, it can be catalyzed by a wide range of compounds including both transition metal complexes [15][16][17][18][19][20][21][22][23][24][25][26][27][28][29][30] and simple inorganics and organocatalysts [31][32][33][34][35]. As the only byproduct of these reaction is molecular hydrogen, they are also considered chemical storage of this element [36], whose capacity greatly varies with the silane being used and can be as high as over 4 wt % [16].…”
Section: Introductionmentioning
confidence: 99%
“…Over the years, direct dehydrogenative coupling of alcohols with hydrosilanes emerged as a green, halogen-free alternative to the former approach. At the moment, it can be catalyzed by a wide range of compounds including both transition metal complexes [15][16][17][18][19][20][21][22][23][24][25][26][27][28][29][30] and simple inorganics and organocatalysts [31][32][33][34][35]. As the only byproduct of these reaction is molecular hydrogen, they are also considered chemical storage of this element [36], whose capacity greatly varies with the silane being used and can be as high as over 4 wt % [16].…”
Section: Introductionmentioning
confidence: 99%
“…Ph2Si(OBn)2 in significantly shorter reactions times, however, elevated heating appears to be a necessary factor in these reactions. 31,36,37 Interestingly, reacting 5 equiv of i PrOH with Ph2SiH2 exclusively yielded Ph2SiH(O i Pr) 25 in quantitative conversion with no evidence of the fully substituted product Ph2Si(O i Pr)2 ( 39 Finally, attempts at coupling alcohols to the tertiary alkyl silane Et3SiH produced no change in 1 H NMR spectroscopy after 24 h.…”
Section: Article Dalton Transactionsmentioning
confidence: 98%
“…Du and co‐workers in 2015 reported salen‐Mn(V) complex Mn‐17 catalyzed ADC of hydrosilanes 7 with 1 and carboxylic acids 6 (Scheme ) . The silanols 8 a and silylesters 8 b were obtained in moderate to excellent yields.…”
Section: Carbon‐heteroatom Bond Formationmentioning
confidence: 99%