The ambiguity of the splitting effect on X80 low-carbon microalloyed pipeline steels’ tendency towards brittle fracture prompted an experimental study of impact toughness scattering based on multiple Charpy impact tests in a temperature range from 20 °C to −100 °C. A fractographic analysis of a large number of fractured samples was carried out. The relationships between impact toughness, deformability and splitting characteristics were studied. A number of common features of three X80 low-carbon microalloyed pipeline steel fractures were revealed. It was experimentally established that the reason for the scattering of the impact toughness values during completely ductile fracture of specimens, as well as during fracture accompanied by the splitting formation, is the local inhomogeneity of plastic properties. The higher the susceptibility to the formation of splits for a particular steel, the lower the impact toughness. Using the electron backscatter diffraction (EBSD) technique, an uneven distribution of local plasticity in the plastic zone of impact-fractured specimens was established. A comparative analysis of specimens with equal impact toughness values at different test temperatures makes it possible to identify the mechanism of negative splitting influence compensation by the increased plasticity of certain specimen.