“…Wherein, hollow multishelled structure (HoMS) with multiple shells and interior cavities, has shown great promise in various application areas, including not only rechargeable batteries, [13–15] but also electromagnetic wave absorption, [16,17] catalysis, [18–20] sensor, [21,22] and drug delivery, [23,24] etc. Especially, as electrode materials for high energy density batteries, HoMS could effectively accommodate the volume change and the stress during charging‐discharging process, thus improving the cyclic stability [25–27] . Additionally, it could shorten the charge diffusion path, [28–30] thus improving the rate capability.…”