2017
DOI: 10.1002/adma.201606099
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Delivery Systems for Low Molecular Weight Payloads: Core/Shell Capsules with Composite Coacervate/Polyurea Membranes

Abstract: Composite polyurea/coacervate core/shell capsules are formed by coupling associative biopolymer phase separation with interfacial polymerization. They combine the excellent chemical stability of synthetic polymer barriers with the strong adhesive properties of protein-based complex coacervates, inspired by biological underwater glues. To encapsulate volatile oil droplets, a primary coacervate hydrogel capsule is formed by a protein and weak polyanion and is reinforced with a polyurea membrane synthesized in si… Show more

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Cited by 39 publications
(33 citation statements)
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“…Most recently, Dardelle et al . () created a composite polyurea/coacervate core/shell capsules, providing an excellent permeability barrier against diffusion of small volatile molecules from volatile oil droplets.…”
Section: Introductionmentioning
confidence: 97%
See 1 more Smart Citation
“…Most recently, Dardelle et al . () created a composite polyurea/coacervate core/shell capsules, providing an excellent permeability barrier against diffusion of small volatile molecules from volatile oil droplets.…”
Section: Introductionmentioning
confidence: 97%
“…Recently, the encapsulation of functional oil by the coacervation method has garnered increasing attention (Eratte et al, 2014;Lv et al, 2014;Ifeduba & Akoh, 2015). Most recently, Dardelle et al (2017) created a composite polyurea/coacervate core/shell capsules, providing an excellent permeability barrier against diffusion of small volatile molecules from volatile oil droplets.…”
Section: Introductionmentioning
confidence: 99%
“…Although several materials of a different nature have been proposed as shells for the encapsulation of fragrances and flavours [ 12 , 13 , 14 ], polymers and cyclodextrins (CDs) still remain the most employed in all technological fields [ 15 ]. Particularly, polymers both of natural or synthetic origin have been reported to successfully encapsulate flavour and fragrances into single or multi-layered core-shell micro- or nanocapsules [ 16 , 17 , 18 ]. These capsules resulted in being highly versatile for the encapsulation of volatile compounds, thanks to the large variety of polymers and methodologies available (e.g., coacervation and interfacial polymerisation), through which their chemical–physical properties can be tuned [ 19 , 20 ].…”
Section: Introductionmentioning
confidence: 99%
“…Delivery systems to load the aroma compounds include polymer, inorganic materials and combined composites thereof 9 . Polymeric capsules (polyacrylate, 10,11 polyurethane, 12 polysaccharide, 13,14 etc) as the most typical delivery system have advantages of light weight, extensive sources and easy processing.For example, acrylates‐dithiol copolymeric microcapsules from interfacial thiol‐ene polymerization in oil‐in‐water emulsion had fragrance oil encapsulation efficiency as 91% and were stable at room temperature 15 . However, the aroma can only be released by destroying the polymeric shells with the mechanical treatments 16,17 .…”
Section: Introductionmentioning
confidence: 99%